Recent Advances in Synthesis and Crystal Structures of Metal Pentazolate Salts

CrystEngComm ◽  
2021 ◽  
Author(s):  
Honglei Xia ◽  
Wenquan Zhang ◽  
Yuteng Cao ◽  
Qinghua Zhang
Keyword(s):  
Crystal Structures ◽  
Membered Ring ◽  
Donor Ligand ◽  
Nitrogen Donor Ligand ◽  
Recent Advances ◽  
Nitrogen Donor

Pentazole is the last member of the azole family. As a five-membered ring constructed by nitrogen, pentazole skeleton is a good nitrogen-donor ligand, which possesses great potential to prepare intriguing...

Oxidation of dimethylplatinum(II) complexes with malonyl peroxide derivatives

2015 ◽  
Vol 93 (1) ◽  
pp. 74-81 ◽  
Author(s):  
Richard J. Hazlehurst ◽  
Kyle R. Pellarin ◽  
Matthew S. McCready ◽  
Richard J. Puddephatt
Keyword(s):  
Phthalic Acid ◽  
Oxidative Addition ◽  
Membered Ring ◽  
Trans Isomers ◽  
Donor Ligand ◽  
Nitrogen Donor Ligand ◽  
Nitrogen Donor ◽  
Dicarboxylate Ligand ◽  
Cis And Trans

The reaction of the cyclic peroxides cyclobutane malonoyl peroxide and cyclopentane malonoyl peroxide to dimethylplatinum(II) complexes with the bidentate nitrogen donor ligand 4,4′-di-t-butyl-2,2′-bipyridine (bubpy) gave a mixture of the products of cis and trans oxidative addition, [PtMe2{(O2C)2C(C3H6)}(bubpy)] and [PtMe2{(O2C)2C(C4H8)}(bubpy)], respectively. The cis isomers exist with a chelating dicarboxylate ligand, forming a six-membered ring, while the trans isomers are thought to exist as oligomers, which may react with water or solvent to give complexes containing a monodentate dicarboxylate ligand. Equilibration of the product of cis oxidative addition, cis-[PtMe2{(O2C)2C(C3H6)}(bubpy)], with oxalic or phthalic acid to give equilibria with the oxalate cis-[PtMe2(O4C2)(bubpy)] or phthalate cis-[PtMe2{(O2C)2C6H4}(bubpy)] derivative, respectively, indicated the expected sequence of chelate stability oxalate > cyclobutane malonate > phthalate.

scholarly journals Nitrogen donor ligand for capping ZnS quantum dots: a quantum chemical and toxicological insight

RSC Advances ◽  
2019 ◽  
Vol 9 (49) ◽  
pp. 28510-28524 ◽  
Author(s):  
Vivek Pandey ◽  
Vinay Kumar Tripathi ◽  
Keshav Kumar Singh ◽  
Tejasvi Bhatia ◽  
Nitesh Kumar Upadhyay ◽  
...  
Keyword(s):  
Quantum Dots ◽  
Electronic Properties ◽  
Quantum Chemical ◽  
Donor Ligand ◽  
Sensor Development ◽  
Nitrogen Donor Ligand ◽  
Optical And Electronic Properties ◽  
Nitrogen Donor

Nanoparticles having strong optical and electronic properties are the most widely used materials in sensor development.

Solvent extraction separation of Cd(II) and Zn(II) with the organophosphorus extractant D2EHPA and the aqueous nitrogen-donor ligand TPEN

2003 ◽  
Vol 70 (1-3) ◽  
pp. 63-71 ◽  
Author(s):  
Kenji Takeshita ◽  
Kunio Watanabe ◽  
Yoshio Nakano ◽  
Masayuki Watanabe
Keyword(s):  
Solvent Extraction ◽  
Donor Ligand ◽  
Nitrogen Donor Ligand ◽  
Nitrogen Donor ◽  
Extraction Separation

Synthesis and 2D-(1H,103Rh)-NMR Study of the First“Non-Classical” Polyhydrido Complex Stabilized by a Nitrogen Donor Ligand

1990 ◽  
Vol 29 (5) ◽  
pp. 548-549 ◽  
Author(s):  
Urs E. Bucher ◽  
Thomas Lengweiler ◽  
Daniel Nanz ◽  
Wolfgang von Philipsborn ◽  
Luigi M. Venazi
Keyword(s):  
Donor Ligand ◽  
Nitrogen Donor Ligand ◽  
Nmr Study ◽  
Nitrogen Donor

Constitutional isomers and stereoisomers of lanthanum(III) complexes of the dimethyl-substituted six-nitrogen-donor ligand C24H30N6 and crystal structure of [La(C24H30N6)(NCS)3(H2O)]·0.5H2O

Polyhedron ◽  
1998 ◽  
Vol 17 (20) ◽  
pp. 3633-3642 ◽  
Author(s):  
F. Benetollo ◽  
G. Bombieri ◽  
W.A. Gootee ◽  
K.K. Fonda ◽  
K.M. Samaria ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Donor Ligand ◽  
Nitrogen Donor Ligand ◽  
Nitrogen Donor
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