Ferrocenyl thiazolidine-2-thione ornamented 1D coordination polymers derived from coinage metal halide and pseudohalide

CrystEngComm ◽  
2021 ◽  
Author(s):  
Ayushi Singh ◽  
Manoj Trivedi ◽  
Gabriele Kociok-Köhn ◽  
Ashish Singh ◽  
Mohd. Muddassir ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Metal Halide ◽  
Coinage Metal

Two new Cu(I) and one Ag(I) coordination polymers have been synthesized using ferrocenyl funtionalized ligand 3-ferrocenyl methyl-thiazolidine-2-thione (L). These polymers composed of [CuCN(L)]n (FcCuCN), [AgCN(L)]n (FcAgCN) and [{CuI(L)}2]n.nCHCl3 (FcCuI) have...

Isolation and Studies of Thioether-functionalized Pyrazole Derived Cu(I)-based Cyclic Trinuclear Complex and Its Coordination Polymers with [Cu2I2] and [BiBr3] Nodes

2021 ◽  
Author(s):  
Zhi-Qing Lin ◽  
Sai-Li Zheng ◽  
Jie-Ying Hu ◽  
Hua-Qun Zhou ◽  
Zihao Feng ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Molecular Level ◽  
Trinuclear Complex ◽  
Coinage Metal ◽  
Trinuclear Complexes

Cu(I)-based cyclic trinuclear complexes (CTCs) represent one of the most intensively investigated candidates in coinage metal-derived CTCs because of their rich photoluminescent properties. Beyond molecular level, coordination polymers built upon...

Versatile structures of group 13 metal halide complexes with 4,4′-bipy: from 1D coordination polymers to 2D and 3D metal–organic frameworks

2015 ◽  
Vol 44 (47) ◽  
pp. 20648-20658 ◽  
Author(s):  
Tatiana N. Sevastianova ◽  
Michael Bodensteiner ◽  
Albina F. Maulieva ◽  
Elena I. Davydova ◽  
Alexander V. Virovets ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Metal Organic Frameworks ◽  
Metal Halide ◽  
Metal Halides ◽  
Group 13 ◽  
Metal Organic ◽  
Halide Complexes ◽  
2D And 3D

The nature of the group 13 metal halides strongly affects the structure of their complexes with 4,4′-bipy.

Synthesis of an expanded pincer ligand and its bimetallic coinage metal complexes

2021 ◽  
Author(s):  
Andie Rebekah Delaney ◽  
Lijuan Yu ◽  
Michelle Coote ◽  
Annie Louise Colebatch
Keyword(s):  
Metal Complexes ◽  
Metal Halide ◽  
Bimetallic Complexes ◽  
Pincer Ligand ◽  
Coinage Metal ◽  
Coinage Metals ◽  
Halide Salts

An expanded pincer ligand tBu-PONNOP (2,7-bis(di-tert-butylphosphinito)-1,8-naphthyridine) has been synthesised and its coordination to coinage metals has been studied. Bimetallic complexes were produced with metal halide salts of the type [M2X2(tBu-PONNOP)]...

scholarly journals New sarcosine–metal halide complexes related to ferroelectric TSCC

CrystEngComm ◽  
2018 ◽  
Vol 20 (28) ◽  
pp. 4012-4019
Author(s):  
Rebecca Clulow ◽  
Philip Lightfoot
Keyword(s):  
Crystal Structures ◽  
Calcium Chloride ◽  
Coordination Polymers ◽  
Metal Halide ◽  
Halide Complexes

A family of sarcosine–metal halide coordination polymers are presented. All have structural similarities to the well-known ferroelectric, tris sarcosine calcium chloride, though all these example have centrosymmetric crystal structures.

Coinage Metal Halide Clusters: From Two-Dimensional Ring to Three-Dimensional Solid-State-Like Structures

ChemPhysChem ◽  
2006 ◽  
Vol 7 (11) ◽  
pp. 2286-2289 ◽  
Author(s):  
Robert P. Krawczyk ◽  
Anton Hammerl ◽  
Peter Schwerdtfeger
Keyword(s):  
Solid State ◽  
Three Dimensional ◽  
Metal Halide ◽  
Two Dimensional ◽  
Coinage Metal

Theoretical insights into the effect of amine and phosphine decoration on the photoluminescence of copper(i) and silver(i) coordination polymers

2014 ◽  
Vol 43 (29) ◽  
pp. 11243-11251 ◽  
Author(s):  
Craig A. Bayse ◽  
Lenora K. Harper ◽  
Jasprina L. Ming ◽  
Robert D. Pike
Keyword(s):  
Dft Calculations ◽  
Coordination Polymers ◽  
Emission Spectra ◽  
Coinage Metal ◽  
Metal Cyanides ◽  
Td Dft

Ligand decoration shifts the excitation and emission spectra of coinage metal cyanides. DFT and TD-DFT calculations are used to identify the MOs involved the transitions that contribute to photoluminescence.

Hydrogen-bonded 3D network of d10-metal halide coordination polymer containing N-(3-pyridinyl) nicotinamide: influence of ligand conformation, halide anions and solvent

CrystEngComm ◽  
2019 ◽  
Vol 21 (16) ◽  
pp. 2691-2701 ◽  
Author(s):  
Zahra Nezhadali Baghan ◽  
Alireza Salimi ◽  
Hossein Eshtiagh-Hosseini ◽  
Allen G. Oliver
Keyword(s):  
Coordination Polymer ◽  
Hydrogen Bonds ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
Metal Halide ◽  
One Dimensional ◽  
Halide Anions ◽  
3D Network ◽  
D10 Metal ◽  
Ligand Conformation

The crystal structures of four new d10-metal halide coordination polymers are determined as one-dimensional (1D) zigzag chains which are in contact with each other by C/N–H⋯X (X = Cl, Br, I) hydrogen bonds.

scholarly journals Group 13 Metal Halide Based Coordination Polymers of Al, Ga, In and 2,4,6‐Tri(4‐pyridyl)‐1,3,5‐triazine

2020 ◽  
Vol 646 (18) ◽  
pp. 1555-1562 ◽  
Author(s):  
Thomas Schäfer ◽  
Alexander E. Sedykh ◽  
Jonathan Becker ◽  
Klaus Müller‐Buschbaum
Keyword(s):  
Coordination Polymers ◽  
Metal Halide ◽  
Group 13
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