scholarly journals Electronic Structure of n-Cycloparaphenylenes Directly Observed by Photoemission Spectroscopy

Author(s):  
Kaname Kanai ◽  
Takuya Inoue ◽  
Takaya Furuichi ◽  
Kaito Shinoda ◽  
Takashi Iwahashi ◽  
...  

A series of n-cycloparaphenylenes ([n]CPP) were studied by ultraviolet photoemission, inverse photoemission, ultraviolet-visible absorption, and X-ray photoemission spectroscopy to detect their unique electronic structures. [n]CPP has a cyclic structure in...

2006 ◽  
Vol 965 ◽  
Author(s):  
Toshio Nishi ◽  
Yasunori Kamizuru ◽  
Kaname Kanai ◽  
Yukio Ouchi ◽  
Kazuhiko Seki

ABSTRACTElectronic structures of the ionic liquids were studied by ultraviolet photoemission spectroscopy (UPS) and inverse photoemission spectroscopy (IPES). The sample materials contain 1-buthyl-3-alkylimidazolium ion [Cnmim]+ (n=4, 8, 10) as the cation in combination with fluorine-containing anions (tetrafluoroboronate BF4−, hexafluorophosphate PF6−). Comparing the calculated density of states with the observed spectra, we found that the ionization thresholds of these ionic liquids are determined by the highest occupied molecular orbitals (HOMO) of the cation, although the calculated HOMOs of the isolated anions are higher than that of isolated cation. The combination of the UPS and IPES results reveals that the band gaps of these ionic liquids are determined by only cation.


2006 ◽  
Vol 74 (15) ◽  
Author(s):  
K. Takubo ◽  
J.-Y. Son ◽  
T. Mizokawa ◽  
H. Ueda ◽  
M. Isobe ◽  
...  

1989 ◽  
Vol 40 (7) ◽  
pp. 4442-4452 ◽  
Author(s):  
Noriaki Hamada ◽  
Sandro Massidda ◽  
Arthur J. Freeman ◽  
Joseph Redinger

1996 ◽  
Vol 54 (8) ◽  
pp. 5471-5479 ◽  
Author(s):  
Ken T. Park ◽  
Michelle Richards-Babb ◽  
James S. Hess ◽  
Jeff Weiss ◽  
Kamil Klier

2010 ◽  
Vol 49 (6) ◽  
pp. 061504 ◽  
Author(s):  
Alo Dutta ◽  
Tripurari Prasad Sinha ◽  
Santiranjan Shannigrahi

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