Pseudotetrahedral Zn(II)-(R or S)-dihalogen-salicylaldiminato complexes with Λ- or Δ-chirality induction at-metal

2022 ◽  
Author(s):  
Hadi Amiri Rudbari ◽  
Arezoo Saadati ◽  
Mahnaz Ariaeefar ◽  
Olivier Blacque ◽  
Isabel Correia ◽  
...  
Keyword(s):  
Chirality Induction

Reactions of enantiopure (S or R)-N-1-(phenyl)ethyl-2,4-X1,X2-salicylaldimine (S-H or R-H; X1, X2 = dihalogen) with Zn(II)-nitrate give bis[(S or R)-N-1-(phenyl)ethyl-2,4-X1,X2-salicylaldiminato-κ2N,O]-zinc(II), (Δ-ZnS or Λ-ZnR) with Δ/Λ-chirality induction at-metal in the C2-symmetric molecules....

Three-Dimensional Morphological Chirality Induction Using High Magnetic Fields in Membrane Tubes Prepared by a Silicate Garden Reaction

2005 ◽  
Vol 109 (28) ◽  
pp. 13445-13450 ◽  
Author(s):  
Wenyong Duan ◽  
Shu Kitamura ◽  
Ichiro Uechi ◽  
Akio Katsuki ◽  
Yoshifumi Tanimoto
Keyword(s):  
Magnetic Fields ◽  
Three Dimensional ◽  
High Magnetic Fields ◽  
Chirality Induction

Mesomorphism, polymerization, and chirality induction in α -cyanostilbene-functionalized diacetylene-assembled films: Photo-triggered Z /E isomerization

2017 ◽  
Vol 55 (15) ◽  
pp. 2458-2466 ◽  
Author(s):  
Yan Zhang ◽  
Jingang Hu ◽  
Guang Yang ◽  
Hongli Zhang ◽  
Qijin Zhang ◽  
...  
Keyword(s):  
Chirality Induction

scholarly journals Chirality Induction in Bioorganometallic Conjugates

Inorganics ◽  
2018 ◽  
Vol 6 (4) ◽  
pp. 111
Author(s):  
Toshiyuki Moriuchi ◽  
Satoshi Ohmura ◽  
Takayo Moriuchi-Kawakami
Keyword(s):  
Hydrogen Bonding ◽  
Organometallic Chemistry ◽  
Organometallic Compounds ◽  
Research Field ◽  
Bioorganometallic Chemistry ◽  
Promising Strategy ◽  
Chiral Centers ◽  
Chirality Induction ◽  
Helical Chirality

Considerable attention has been given to the research field of bioorganometallic chemistry, which is a hybrid chemistry field between biology and organometallic chemistry. The introduction of biomolecules, which have hydrogen bonding sites and chiral centers, into organometallic compounds is a promising strategy to construct chirality-organized bioorganometallic conjugates. This feature paper sketches an outline of induction of helical chirality into bioorganometallic conjugates by the control of a torsional twist of the organometallic moiety. Topics covered included control of the helical chirality of 1,n′-disubstituted ferrocene moieties in ferrocene-dipeptide conjugates, and the chirality induction of the Au(I)–Au(I) axis in the dinuclear organogold(I)-uracil conjugates.

Cyclic Peptoids as Topological Templates: Synthesis via Central to Conformational Chirality Induction

2018 ◽  
Vol 20 (3) ◽  
pp. 640-643 ◽  
Author(s):  
Assunta D’Amato ◽  
Giovanni Pierri ◽  
Chiara Costabile ◽  
Giorgio Della Sala ◽  
Consiglia Tedesco ◽  
...  
Keyword(s):  
Chirality Induction

The More the Slower: Self-Inhibition in Supramolecular Chirality Induction, Memory, Erasure, and Reversion

2022 ◽  
Author(s):  
Jiecheng Ji ◽  
Xueqin Wei ◽  
Wanhua Wu ◽  
Chunying Fan ◽  
Dayang Zhou ◽  
...  
Keyword(s):  
Supramolecular Chirality ◽  
Chirality Induction

An effective strategy for creating asymmetric MOFs for chirality induction: a chiral Zr-based MOF for enantioselective epoxidation

2019 ◽  
Vol 9 (13) ◽  
pp. 3388-3397 ◽  
Author(s):  
Kayhaneh Berijani ◽  
Ali Morsali ◽  
Joseph T. Hupp
Keyword(s):  
Tartaric Acid ◽  
Effective Strategy ◽  
Rapid Procedure ◽  
Enantioselective Epoxidation ◽  
Chirality Induction

A simple and rapid procedure was used to prepare chiral NU-1000 as a robust Zr-based MOF without complexity. The functionalization of NU-1000 was performed by utilizing chirall-(+)-tartaric acidviasolvent-assisted linker incorporation, resulting in [C-NU-1000]. A Mo-complex was immobilized onto chiral NU-1000 for enantioselective epoxidation.

Chirality Induction and Protonation-Induced Molecular Motions in Helical Molecular Strands

2007 ◽  
Vol 13 (19) ◽  
pp. 5466-5479 ◽  
Author(s):  
Elena Kolomiets ◽  
Volker Berl ◽  
Jean-Marie Lehn
Keyword(s):  
Molecular Motions ◽  
Chirality Induction

3D-Morphological Chirality Induction in Zinc Silicate Membrane Tube Using a High Magnetic Field

2004 ◽  
Vol 108 (8) ◽  
pp. 2527-2530 ◽  
Author(s):  
Ichiro Uechi ◽  
Akio Katsuki ◽  
Lev Dunin-Barkovskiy ◽  
Yoshifumi Tanimoto
Keyword(s):  
Magnetic Field ◽  
High Magnetic Field ◽  
Zinc Silicate ◽  
Membrane Tube ◽  
Chirality Induction
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