A Unified Total Synthesis of Benzo[d][1,3]dioxole-type Benzylisoquinoline Alkaloids of Aporphines, Coptisines, and Dibenzopyrrocolines
The first total synthesis of (S)-(+)-ovigerine, (S)-(+)-N-formylovigerine, and (6aS,6a'S)-(+)-ovigeridimerine of aporphine alkaloids with benzo[d][1,3]dioxole structure feature was established. The strategy was based upon the well known Pd-catalyzed arylation to set...
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