A Metal-Free Strategy for the Cross-Dehydrogenative Coupling of the 1, 3-Dicarbonyl Compounds with 2-Methoxyethanol

The Cross

Here, we report a metal-free approach for the construction of methylene-bridged bis-1,3-dicarbonyl compounds via cross-dehydrogenative coupling of 1,3-dicarbonyl compounds with 2-methoxyethanol. In addition, we have extended this methodology to synthesize...

Latest Advancements in Transition‐Metal‐Free Carbon‐Heteroatom Bond Formation Reactions via Cross‐ Dehydrogenative Coupling

Asian Journal of Organic Chemistry ◽

10.1002/ajoc.202100070 ◽

2021 ◽

Author(s):

Aanchal Batra ◽

Pushpinder Singh ◽

Kamal Nain Singh

Keyword(s):

Transition Metal ◽

Bond Formation ◽

Free Carbon ◽

Metal Free ◽

Bond Formation Reactions

Synthesis of Polycyclic Amines through Mild Metal-Free Tandem Cross-Dehydrogenative Coupling/Intramolecular Hydroarylation ofN-Aryltetrahydroisoquinolines and Crotonaldehyde

European Journal of Organic Chemistry ◽

10.1002/ejoc.201403375 ◽

2014 ◽

Vol 2015 (3) ◽

pp. 468-473 ◽

Cited By ~ 12

Author(s):

Xiang Wu ◽

Dian-Feng Chen ◽

Shu-Sen Chen ◽

Yi-Fan Zhu

Keyword(s):

Metal Free ◽

ChemInform Abstract: Di-tert-butyl Peroxide (DTBP) Promoted Dehydrogenative Coupling: An Expedient and Metal-Free Synthesis of Oxindoles via Intramolecular C(sp2)-H and C(sp3)-H Bond Activation.

ChemInform ◽

10.1002/chin.201604106 ◽

2016 ◽

Vol 47 (4) ◽

pp. no-no

Author(s):

Biplab Mondal ◽

Brindaban Roy

Keyword(s):

Bond Activation ◽

Metal Free ◽

Tert Butyl ◽

Butyl Peroxide

Bifunctional metal-free photo-organocatalysts for enantioselective aerobic oxidation of β-dicarbonyl compounds

Tetrahedron ◽

10.1016/j.tet.2018.05.023 ◽

2018 ◽

Vol 74 (27) ◽

pp. 3624-3633 ◽

Cited By ~ 9

Author(s):

Xiao-fei Tang ◽

Shi-hao Feng ◽

Ya-kun Wang ◽

Fan Yang ◽

Ze-hao Zheng ◽

...

Keyword(s):

Aerobic Oxidation ◽

Dicarbonyl Compounds ◽

Metal Free

ChemInform Abstract: Metal Free TBHP-Promoted Intramolecular Carbonylation of Arenes via Radical Cross-Dehydrogenative Coupling: Synthesis of Indenoquinolinones, 4-Azafluorenones and Fluorenones.

ChemInform ◽

10.1002/chin.201646027 ◽

2016 ◽

Vol 47 (46) ◽

Author(s):

Kalpana Mishra ◽

Ashok Kumar Pandey ◽

Jay Bahadur Singh ◽

Radhey M. Singh

Keyword(s):

Metal Free ◽

Metal-Free Visible-Light-Induced C–H/C–H Cross-Dehydrogenative-Coupling of Quinoxalin-2(H)-ones with Simple Ethers

ACS Sustainable Chemistry & Engineering ◽

10.1021/acssuschemeng.8b04652 ◽

2018 ◽

Vol 6 (12) ◽

pp. 17252-17257 ◽

Cited By ~ 79

Author(s):

Wei Wei ◽

Leilei Wang ◽

Huilan Yue ◽

Pengli Bao ◽

Weiwei Liu ◽

...

Keyword(s):

Visible Light ◽

Metal Free ◽

ChemInform Abstract: DIAD-Mediated Metal-Free Cross Dehydrogenative Coupling Between Tertiary Amines and α-Fluorinated Sulfones.

ChemInform ◽

10.1002/chin.201344089 ◽

2013 ◽

Vol 44 (44) ◽

pp. no-no

Author(s):

Weizhou Huang ◽

Chuanfa Ni ◽

Yanchuan Zhao ◽

Jinbo Hu

Keyword(s):

Tertiary Amines ◽

Metal Free ◽

Iminoiodane- and Brønsted Base-Mediated Cross Dehydrogenative Coupling of Cyclic Ethers with 1,3-Dicarbonyl Compounds

Molecules ◽

10.3390/molecules200713336 ◽

2015 ◽

Vol 20 (7) ◽

pp. 13336-13353 ◽

Cited By ~ 5

Author(s):

Ciputra Tejo ◽

Xiao Sim ◽

Bo Lee ◽

Benjamin Ayers ◽

Chung-Hang Leung ◽

...

Keyword(s):

Cyclic Ethers ◽

Dicarbonyl Compounds ◽

Brønsted Base

Visible-Light-Mediated Cross Dehydrogenative Coupling of Thiols with Aldehydes: Metal-Free Synthesis of Thioesters at Room Temperature

The Journal of Organic Chemistry ◽

10.1021/acs.joc.1c02111 ◽

2021 ◽

Author(s):

Vishal Jyoti Roy ◽

Partha Pratim Sen ◽

Sudipta Raha Roy

Keyword(s):

Visible Light ◽

Room Temperature ◽

Metal Free ◽

A Formal Metal-Free γ-Arylation of 1,3-Dicarbonyl Compounds via a Sequence of Isomerization/1,4-Addition/[3,3]-Sigmatropic Rearrangement

Green Chemistry ◽

10.1039/d1gc02856a ◽

2021 ◽

Author(s):

Shi-Chao Lu ◽

Fuqiang Wen ◽

Xidong Guan

Keyword(s):

Sigmatropic Rearrangement ◽

Mechanistic Studies ◽

Dicarbonyl Compounds ◽

Metal Free

A metal-free redox arylation of alkynes with sulfoxides has been developed to provide an unconventional access to diverse γ-arylated 1,3-dicarbonyl compounds in an atom-economical manner. Mechanistic studies suggest that a...