Synergistic photoredox and tertiary amine catalysis: Generation of allylic sulfones from Morita-Baylis-Hillman acetates and sulfur dioxide

2021 ◽  
Author(s):  
Xinhua Wang ◽  
Ruixiu Liu ◽  
Qiuping Ding ◽  
Wei Xiao ◽  
Jie Wu
Keyword(s):  
Sulfur Dioxide ◽  
Tertiary Amine ◽  
Amine Catalysis

The first example for the synthesis of allylic sulfones through synergistic photoredox and tertiary amine catalysis, starting from MBH acetates, DABCO·(SO2)2 and 4-substituted Hantzsch esters or potassium alkyltrifluoroborates via a...

Dual Palladium(II)/Tertiary Amine Catalysis for Asymmetric Regioselective Rearrangements of Allylic Carbamates

2016 ◽  
Vol 22 (16) ◽  
pp. 5767-5777 ◽  
Author(s):  
Johannes Moritz Bauer ◽  
Wolfgang Frey ◽  
René Peters
Keyword(s):  
Tertiary Amine ◽  
Amine Catalysis

Tertiary Amine Catalysis of The Aldol Condensation

1962 ◽  
Vol 84 (19) ◽  
pp. 3775-3777 ◽  
Author(s):  
C. David. Gutsche ◽  
Rudolf S. Buriks ◽  
Kurt. Nowotny ◽  
Hans. Grassner
Keyword(s):  
Tertiary Amine ◽  
Aldol Condensation ◽  
Amine Catalysis

Sequential Au(i)/chiral tertiary amine catalysis: a tandem C–H functionalization of anisoles or a thiophene/asymmetric Michael addition sequence to quaternary oxindoles

2016 ◽  
Vol 52 (12) ◽  
pp. 2537-2540 ◽  
Author(s):  
Zhong-Yan Cao ◽  
Yu-Lei Zhao ◽  
Jian Zhou
Keyword(s):  
Tertiary Amine ◽  
Michael Addition ◽  
Enantioselective Synthesis ◽  
Asymmetric Michael Addition ◽  
Amine Catalysis

We report an unprecedented sequential Au(i)/bifunctional tertiary amine catalysis, which enables a tandem C–H functionalization of weak nucleophiles (anisoles or thiophenes) and asymmetric Michael addition for the highly enantioselective synthesis of quaternary oxindoles.

scholarly journals Synthesis of Oxazolidinone and Tosyl Enamines by Tertiary Amine Catalysis

Synlett ◽  
2011 ◽  
Vol 2011 (05) ◽  
pp. 699-701
Author(s):  
Gabriel Fenteany ◽  
Nicholas Eddy ◽  
Peter Morse ◽  
Martha Morton
Keyword(s):  
Tertiary Amine ◽  
Amine Catalysis

Asymmetric sequential Au(i)/chiral tertiary amine catalysis: an enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles

2016 ◽  
Vol 52 (20) ◽  
pp. 3943-3946 ◽  
Author(s):  
Yu-Lei Zhao ◽  
Zhong-Yan Cao ◽  
Xing-Ping Zeng ◽  
Jia-Meng Shi ◽  
Yi-Hua Yu ◽  
...  
Keyword(s):  
Tertiary Amine ◽  
Optically Active ◽  
Trimethylsilyl Cyanide ◽  
Amine Catalysis

A gold-catalyzed enone-formation and asymmetric cyanosilylation sequence is developed, providing enantioenriched 3-alkenyloxindoles from diazooxindoles, furans and trimethylsilyl cyanide (TMSCN).

Protecting Group-Directed Diastereodivergent Synthesis of Chiral Tetrahydronaphthalene-Fused Spirooxindoles via Bifunctional Tertiary Amine Catalysis

2019 ◽  
Vol 84 (16) ◽  
pp. 10349-10361 ◽  
Author(s):  
Biao Wang ◽  
Xiao-Hui Wang ◽  
Wei Huang ◽  
Jin Zhou ◽  
Hong-Ping Zhu ◽  
...  
Keyword(s):  
Tertiary Amine ◽  
Protecting Group ◽  
Amine Catalysis
Sign in / Sign up

Export Citation Format

Share Document