scholarly journals Synthesis and characterization of biobased thermoplastic polyester elastomers containing Poly(butylene 2,5-furandicarboxylate)

RSC Advances ◽  
2021 ◽  
Vol 11 (25) ◽  
pp. 14932-14940
Author(s):  
Hailan Kang ◽  
Xiaoli Miao ◽  
Jiahuan Li ◽  
Donghan Li ◽  
Qinghong Fang

A series of sustainable and reprocessible thermoplastic polyester elastomers P(BF-PBSS)s were synthesized using dimethyl-2,5-furandicarboxylate, 1,4-butanediol, and synthetic low-molecular-weight biobased polyester (PBSS).

RSC Advances ◽  
2013 ◽  
Vol 3 (34) ◽  
pp. 14528 ◽  
Author(s):  
Manoharan Mathiselvam ◽  
Duraikkannu Loganathan ◽  
Babu Varghese

2013 ◽  
Vol 460-461 ◽  
pp. 70-77 ◽  
Author(s):  
J.L. Diez de Tuesta ◽  
E. Casas ◽  
J. Moreno ◽  
P. Perez Nebreda ◽  
J.M. Escola ◽  
...  

2002 ◽  
Vol 34 (1) ◽  
pp. 49-63 ◽  
Author(s):  
C. S. Proikakis ◽  
P. A. Tarantili ◽  
A. G. Andreopoulos

2017 ◽  
Vol 90 (2) ◽  
pp. 308-324 ◽  
Author(s):  
Taejun Yoo ◽  
Steven K. Henning

ABSTRACT A bio-based route to the production of trans-β-farnesene has recently been commercialized. Trans-β-farnesene is capable of being polymerized by both anionic and cationic pathways, creating low molecular weight polymers with structure–property relationships unique within the diene class of monomers. Trans-β-farnesene is produced through fermentation of sugar feedstocks. The pathway offers an alternative to petroleum-based feedstocks derived as by-products of naphtha or ethane cracking. Anionic polymerization of the monomer produces a highly branched “bottlebrush” structure, with rheological properties that are markedly different than those of linear diene polymers. Specifically, a lack of entanglements is observed even at relatively high molar masses. For hydroxyl-terminated oligomers, Tg as a function of molar mass follows a trend opposite non-functional materials. The synthesis and characterization of trans-β-farnesene–based polymers will be presented, including anionically prepared low molecular weight diols and monols.


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