scholarly journals A highly efficient rod-like-CeO2-supported palladium catalyst for the oxidative carbonylation of glycerol to glycerol carbonate

RSC Advances ◽  
2021 ◽  
Vol 11 (28) ◽  
pp. 17072-17079
Author(s):  
Ziyan Wang ◽  
Shuo Guo ◽  
Zhimiao Wang ◽  
Fang Li ◽  
Wei Xue ◽  
...  

Pd/CeO2-r was prepared by a two-step hydrothermal-impregnation method for oxidative carbonylation of glycerol. It exhibited high activity, and glycerol conversion was 93% and glycerol carbonate selectivity was 98% with a TOF of 1240 h−1 under optimized conditions.

RSC Advances ◽  
2017 ◽  
Vol 7 (55) ◽  
pp. 34618-34623 ◽  
Author(s):  
Weichuan Xu ◽  
Litao Yan ◽  
Huiqiang Wang ◽  
Steven Liaw ◽  
Hongmei Luo

Pd nanoparticles anchored on Nb-doped TiO2 with functionalized carbon support (denoted as Pd/Nb–TiO2–C) is synthesized through a controllable hydrolysis and impregnation method.


2019 ◽  
Vol 43 (5-6) ◽  
pp. 189-195 ◽  
Author(s):  
Wencheng Huang ◽  
Jianying Li ◽  
Qiurong Chen ◽  
Mingzhong Cai

A highly efficient heterogeneous palladium-catalyzed transfer semihydrogenation of internal alkynes was achieved in dimethylformamide at 145 ºC by using an MCM-41-immobilized bidentate nitrogen palladium(II) complex [MCM-41-2N-Pd(OAc)2] as catalyst and dimethylformamide/KOH as hydrogen source, yielding a variety of cis-alkenes in good to high yields with excellent stereoselectivity. This supported palladium catalyst can be easily recovered by filtration of the reaction solution and recycled up to seven times with almost consistent activity.


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