scholarly journals Facilitated inversion complicates the stereodynamics of an SN2 reaction at nitrogen center

2021 ◽  
Author(s):  
Dóra Papp ◽  
Gábor Czakó
Keyword(s):  
Sn2 Reaction ◽  
Nitrogen Center

Multiple-inversion, the analogue of the double-inversion pathway recently revealed for SN2@C, is the key mechanism in SN2 at N center undermining stereospecificity.

Newly proposed proton-abstraction roundabout with backside attack mechanism for the SN2 reaction at the nitrogen center in F− + NH2Cl

2018 ◽  
Vol 20 (17) ◽  
pp. 12106-12111 ◽  
Author(s):  
Yongfang Li ◽  
Dunyou Wang
Keyword(s):  
Reaction Mechanisms ◽  
Proton Abstraction ◽  
Sn2 Reaction ◽  
Nitrogen Center

Two novel reaction mechanisms are revealed for the SN2 reaction at the nitrogen center in the F− + NH2Cl reaction.

A water-soluble naphthalenediimide-containing hexacationic cage

2021 ◽  
Author(s):  
Hao Li ◽  
Feihe Huang ◽  
Shuai Fang ◽  
Errui Li ◽  
Dingsheng Zhu ◽  
...  
Keyword(s):  
Water Soluble ◽  
Chromatographic Purification ◽  
One Pot ◽  
Sn2 Reaction

A water-soluble cage containing three naphthalenediimide (NDI) units was synthesized in a one-pot manner without chromatographic purification, during which six irreversible C−N bonds formed simultaneously via SN2 reaction. The cage...

scholarly journals Concurrent Phenomena at the Reaction Path of the SN2 Reaction CH3Cl + F−. Information Planes and Statistical Complexity Analysis

Entropy ◽  
2013 ◽  
Vol 15 (12) ◽  
pp. 4084-4104 ◽  
Author(s):  
Moyocoyani Molina-Espíritu ◽  
Rodolfo Esquivel ◽  
Juan Angulo ◽  
Jesús Dehesa
Keyword(s):  
Complexity Analysis ◽  
Reaction Path ◽  
Statistical Complexity ◽  
Sn2 Reaction

Development of chiral bisphosphoric acid/Boronic acid Co-catalyst system for enantioselective SN2’ reaction

Tetrahedron ◽  
2021 ◽  
pp. 132412
Author(s):  
Satavisha Kayal ◽  
Jun Kikuchi ◽  
Naoya Shinagawa ◽  
Shigenobu Umemiya ◽  
Masahiro Terada
Keyword(s):  
Boronic Acid ◽  
Catalyst System ◽  
Co Catalyst ◽  
Sn2 Reaction

scholarly journals Effect of Lithium Compounds on the SN2 Reaction of Anionic Living Polyisoprene with 4-Bromobutoxy-tert-butyldimethylsilane in Heptane

2010 ◽  
Vol 6 ◽  
pp. 1-8
Author(s):  
Katsuhiko Takenaka ◽  
Kazuhiko Koyasu ◽  
Kohei Yamamoto ◽  
Masamitsu Miya ◽  
Hiroki Takeshita ◽  
...  
Keyword(s):  
Lithium Compounds ◽  
Sn2 Reaction

Microhydration effects on a model SN2 reaction in a nonpolar solvent

2009 ◽  
Vol 130 (19) ◽  
pp. 194502 ◽  
Author(s):  
Katherine V. Nelson ◽  
Ilan Benjamin
Keyword(s):  
Nonpolar Solvent ◽  
Sn2 Reaction
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