scholarly journals A Rare Earth Metallocene Containing a 2,2’-Azopyridyl Radical Anion

2021 ◽  
Author(s):  
Francis Delano IV ◽  
Ernesto Castellanos ◽  
John McCracken ◽  
Selvan Demir
Keyword(s):  
Rare Earth ◽  
Metal Ions ◽  
Rare Earth Metal ◽  
Radical Anion ◽  
Earth Metal ◽  
Organic Ligands ◽  
Direct Exchange

Introducing spin onto organic ligands that are coordinated to rare earth metal ions allows direct exchange with metal spin centres. This is particularly relevant for the deeply buried 4f-orbitals of...

Phosphorylated-calix[4]arene double-deckers of single rare earth metal ions

2021 ◽  
Author(s):  
Marjan Hosseinzadeh ◽  
Sergio Sanz ◽  
Jan van Leusen ◽  
Natalya V Izarova ◽  
Euan K Brechin ◽  
...  
Keyword(s):  
Rare Earth ◽  
Metal Ions ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Double Decker ◽  
Organic Framework

Combination of phosphoryl and calix[4]arene moieties in the same organic framework (LPO) directs the formation of homoleptic double-decker complexes [LnIII(LPO)2](O3SCF3)3 for Ln = Tb and Dy, with the latter displaying...

Peptide Hydrogel with Antibacterial Performance Induced by Rare Earth Metal Ions

Langmuir ◽  
2021 ◽  
Author(s):  
Wenlong Xu ◽  
Zhiwen Zhang ◽  
Xin Zhang ◽  
Yuanhan Tang ◽  
Yuzhong Niu ◽  
...  
Keyword(s):  
Rare Earth ◽  
Metal Ions ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Antibacterial Performance ◽  
Peptide Hydrogel

scholarly journals Isolation of +2 rare earth metal ions with three anionic carbocyclic rings: bimetallic bis(cyclopentadienyl) reduced arene complexes of La2+ and Ce2+ are four electron reductants

2015 ◽  
Vol 6 (12) ◽  
pp. 7267-7273 ◽  
Author(s):  
Christopher M. Kotyk ◽  
Megan E. Fieser ◽  
Chad T. Palumbo ◽  
Joseph W. Ziller ◽  
Lucy E. Darago ◽  
...  
Keyword(s):  
Rare Earth ◽  
Metal Ions ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Arene Complexes ◽  
Carbocyclic Rings

A new option for stabilizing unusual Ln2+ ions has been identified in the reaction of (C5H4SiMe3)3Ln (Ln = La, Ce) with potassium graphite and 2.2.2-cryptand in benzene.

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