Measurements of the rate of radical desorption from polymer latices during emulsion polymerisation

1981 ◽  
Vol 77 (11) ◽  
pp. 2659 ◽  
Author(s):  
B. W. Brooks ◽  
B. O. Makanjuola
Keyword(s):  
Emulsion Polymerisation ◽  
Polymer Latices

Facile synthesis of gemini surface-active ATRP initiator and its use in soap-free AGET ATRP mini-emulsion polymerisation

2013 ◽  
Vol 67 (3) ◽  
Author(s):  
Chuan Cheng ◽  
Quan Fu ◽  
Xiong Bai ◽  
Shao Liu ◽  
Liang Shen ◽  
...  
Keyword(s):  
Gemini Surfactant ◽  
Reaction Kinetic ◽  
Total Yield ◽  
Kinetic Studies ◽  
Facile Synthesis ◽  
Aget Atrp ◽  
Cationic Gemini Surfactant ◽  
Emulsion Polymerisation ◽  
Radical Polymerisation ◽  
Surface Active

AbstractA novel cationic gemini surfactant has been readily synthesised in 70 % total yield. The functional gemini surfactant can act both as an emulsifier and an atom transfer radical polymerisation (ATRP) initiator in mini-emulsion polymerisation of methyl methacrylate (MMA), in which no other emulsifier was required. 1-(Dimethylamino)dodecane (N,N-dimethyldodecylamine, DMDA) was found to be a good ligand in the activator generated by electron transfer (AGET) ATRP reaction. Kinetic studies indicated that the polymerisation featured controlled/living radical polymerisation.

A new technique for the cleaning of polymer latices

1981 ◽  
Vol 79 (1) ◽  
pp. 272-277 ◽  
Author(s):  
M.C Wilkinson ◽  
D Fairhurst
Keyword(s):  
New Technique ◽  
Polymer Latices ◽  
A New Technique
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