Infrared spectra of tetrahedral oxyanions of the transition metals

1966 ◽  
pp. 1467 ◽  
Author(s):  
W. P. Griffith
Keyword(s):  
Transition Metals ◽  
Infrared Spectra ◽  
Tetrahedral Oxyanions

Electronic and infrared spectra of biguanide complexes of the 3d-transition metals

1974 ◽  
Vol 36 (12) ◽  
pp. 3685-3688 ◽  
Author(s):  
P.V. Babykutty ◽  
C.P. Prabhakaran ◽  
R. Anantaraman ◽  
C.G.R. Nair
Keyword(s):  
Transition Metals ◽  
Infrared Spectra

The Synthesis of 4-Substituted 4-Vinylcyclohexenes and Their Promise as Complex Ion Ligands

1969 ◽  
Vol 24 (5) ◽  
pp. 530-531 ◽  
Author(s):  
Donald Chinn ◽  
Herschel Frye
Keyword(s):  
Complex Formation ◽  
Transition Metals ◽  
Infrared Spectra ◽  
Analytical Data ◽  
Complex Ions ◽  
Elemental Analyses ◽  
Grignard Reactions ◽  
Complex Ion

Many diolefins serve as ligands for the formation of complex ions with transition metals; some of these ligands undergo isomerization during complex formation (1.2). This paper reports the synthesis of a series of 4-substituted 4-vinylcyclohexenes which may function as pi bonding donors and may undergo rearrangement. The syntheses were carried out via Grignard reactions using 4-bromo-4-vinylcyclohexene, a previously unreported compound. Analytical data are given including elemental analyses, infrared spectra, and NMR findings for several compounds.

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