Recent Advances in Transition-Metal-Catalyzed Silylations of Arenes with Hydrosilanes: C–X Bond Cleavage or C–H Bond Activation­ Synchronized with Si–H Bond Activation

Synthesis ◽  
2015 ◽  
Vol 47 (23) ◽  
pp. 3645-3668 ◽  
Author(s):  
Zheng Xu ◽  
Li-Wen Xu ◽  
Wei-Sheng Huang ◽  
Jin Zhang
RSC Advances ◽  
2014 ◽  
Vol 4 (88) ◽  
pp. 47806-47826 ◽  
Author(s):  
Qiaodong Wen ◽  
Ping Lu ◽  
Yanguang Wang

Recent advances in transition-metal-catalyzed C–CN bond activation, leading to a lot of important approaches such as cyanofunctionalization, cross-coupling and cyanation, are reviewed.


2014 ◽  
Vol 1 (7) ◽  
pp. 838-842 ◽  
Author(s):  
Guobing Yan ◽  
Arun Jyoti Borah

Chemical transformations via catalytic C–H bond activation have been established as one of the most powerful tools in organic synthetic chemistry. Transition-metal-catalyzed direct functionalization of β-C(sp3)–H bonds of carbonyl compounds has been developed in recent years. This highlight will focus on recent advances in this active area and their mechanisms are also discussed.


2020 ◽  
Vol 7 (19) ◽  
pp. 3067-3099
Author(s):  
Biao Nie ◽  
Wanqing Wu ◽  
Yingjun Zhang ◽  
Huanfeng Jiang ◽  
Ji Zhang

An update on recent advances in the synthesis of bridgehead nitrogen fused heterocycles via transition metal-catalyzed C–H activation and functionalization is reported.


2015 ◽  
Vol 2 (2) ◽  
pp. 169-178 ◽  
Author(s):  
Guanyinsheng Qiu ◽  
Jie Wu

This review is focused on the recent advances in the transition metal-catalyzed direct remote C–H-functionalization of alkyl groups via C(sp3)–H bond activation. In general, carboxamide/ester-chelated β-functionalization reactions are summarized.


Synlett ◽  
2021 ◽  
Author(s):  
Tao Xiong ◽  
Qian Zhang ◽  
Qian Zhang

AbstractThe polyfluoroarenes are a subgroup of organofluorines that are widely utilized in both medicinal chemistry and materials science. We briefly summarize recent advances in the synthesis of these important compounds, with particular attention to our recent CuH-catalyzed defluorinative alkylation of polyfluoroarenes with alkenes in a highly site-selective C–F bond-cleavage fashion.1 Introduction2 Transition-Metal-Catalyzed Alkylation through Selective C–F Bond Cleavage3 CuH-Catalyzed Defluorinative Alkylation of Polyfluoroarenes with Alkenes4 Summary and Outlook


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