Sulfonium-Salt Based Trifluoromethylating Reagent Permits Multiple Reactivity Paradigms

Synfacts ◽  
2021 ◽  
Vol 18 (01) ◽  
pp. 0018
Keyword(s):  
2021 ◽  
pp. 110525
Author(s):  
Shixiong Chen ◽  
Chun Cao ◽  
Xiaoming Shen ◽  
Yiwei Qiu ◽  
Cuifang Kuang ◽  
...  
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2014 ◽  
Vol 43 (9) ◽  
pp. 3424-3427
Author(s):  
D. E. Janzen ◽  
A. M. Kooyman

A trithiamacrocyclic ligand complex of Au(iii) undergoes a redox-mediated thermal reaction to form a chiral bicyclic sulfonium salt.


1996 ◽  
Vol 51 (2) ◽  
pp. 277-285
Author(s):  
Rolf Minkwitz ◽  
Ulrike Lohmann ◽  
Hans Preut

Abstract The synthesis of salts of the type RnSH3-n+MF6- (R = C2H5, i-C3H7; n = 1, 2; M = As, Sb) by protonation of the corresponding thiols and sulfides in the superacid systems HF/MF5 is reported. The salts have been characterized by vibrational and NMR spectroscopic methods. Isopropylsulfonium hexafluoroantimonate is the first known example of a sulfonium salt, for which a SH bond distance has been determined by a crystal structure analysis, i-C3H7SH2+SbF6- crystallizes in the monoclinic space group P21/m with a = 568.0(4), b = 801.1(6), c = 1019.7(8) pm, β = 82.63(6) °, with two formula units per unit cell.


2016 ◽  
Vol Volume 11 ◽  
pp. 6161-6168 ◽  
Author(s):  
Alaa A Fadhel ◽  
Xiling Yue ◽  
Ebrahim H Ghazvini Zadeh ◽  
Mykhailo Bondar ◽  
Kevin D Belfield

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