Improved Procedure for the Selective Reduction of Carbonyl Compounds and Carboxylic Acid Esters by Potassium Salt-Induced Hydrosilylation

Synthesis ◽  
2002 ◽  
Vol 1982 (11) ◽  
pp. 981-984 ◽  
Author(s):  
C. Chuit ◽  
R. Corriu ◽  
R. Perz ◽  
C. Reyé
Keyword(s):  
Carboxylic Acid ◽  
Carbonyl Compounds ◽  
Potassium Salt ◽  
Selective Reduction ◽  
Acid Esters

New One-Pot Preparation of α,β-Unsaturated Carboxylic Acid Esters from Carbonyl Compounds

Synthesis ◽  
1988 ◽  
Vol 1988 (07) ◽  
pp. 537-538 ◽  
Author(s):  
George A. Olah ◽  
An-hsiang Wu ◽  
Omar Farooq ◽  
G. K. Surya Prakash
Keyword(s):  
Carboxylic Acid ◽  
Carbonyl Compounds ◽  
One Pot ◽  
Unsaturated Carboxylic Acid ◽  
Acid Esters

m-Carborane-C-carboxylic acid esters derived from some terpene alcohols, sterols, plant phenols, and oximes of natural carbonyl compounds

2008 ◽  
Vol 44 (9) ◽  
pp. 1305-1310 ◽  
Author(s):  
E. A. Dikusar ◽  
V. I. Potkin ◽  
N. G. Kozlov ◽  
A. P. Yuvchenko ◽  
M. P. Bei ◽  
...  
Keyword(s):  
Carboxylic Acid ◽  
Carbonyl Compounds ◽  
Plant Phenols ◽  
Terpene Alcohols ◽  
Acid Esters

Ketones from Nickel-Catalyzed Decarboxylative, Non-Symmetric Cross-Electrophile Coupling of Carboxylic Acid Esters

2019 ◽  
Author(s):  
Jiang Wang ◽  
Brian P. Cary ◽  
Peyton Beyer ◽  
Samuel H. Gellman ◽  
Daniel Weix
Keyword(s):  
Carboxylic Acid ◽  
Solid Support ◽  
Reaction Conditions ◽  
Decarboxylative Coupling ◽  
New Strategy ◽  
The Cross ◽  
Acyl Donors ◽  
Acid Esters

A new strategy for the synthesis of ketones is presented based upon the decarboxylative coupling of N-hydroxyphthalimide (NHP) esters with S-2-pyridyl thioesters. The reactions are selective for the cross-coupled product because NHP esters act as radical donors and the thioesters act as acyl donors. The reaction conditions are general and mild, with over 40 examples presented, including larger fragments and the 20-mer peptide Exendin(9-39) on solid support.

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