Improved high‐intensity microwave discharge lamp for atomic resonance absorption and fluorescence spectrometry

1978 ◽  
Vol 49 (9) ◽  
pp. 1322-1323 ◽  
Author(s):  
Assa Lifshitz ◽  
Gordon B. Skinner ◽  
David R. Wood
Author(s):  
N. S. Bystrov ◽  
◽  
A. V. Emelianov ◽  
A. V. Eremin ◽  
P. I. Yatsenko ◽  
...  

The kinetics of reaction of C2H5OH with N2O behind shock waves is studied. The quantitative measurements of the time profiles of concentration of O atoms were carried out by the method of atomic resonance absorption spectroscopy (ARAS) using resonance vacuum-ultraviolet line of O-atom at 130.5 nm. For the calibration of absorption intensity of oxygen atoms depending on its concentration, the special series of experiments in the mixture containing different amounts of N2O in Ar was carried out at T = 2100 ± 50 K when molecule of N2O is completely dissociated. An experimental study of the appearance and consumption of oxygen atoms during the reaction of ethanol with oxygen in mixture 10 ppm N2O + (10 ... 0.1) ppm C2H5OH + Ar at temperatures of 16002300 K and pressures of 200-300 kPa have been carried out. A kinetic analysis of obtained data was performed using the Chemkin package.


1998 ◽  
Vol 16 (1) ◽  
pp. 101-113 ◽  
Author(s):  
D. Riley ◽  
R.A. Smith ◽  
A. J. MacKinnon ◽  
O. Willi ◽  
M.H.R. Hutchinson

The interaction of short (1−2 ps) laser pulses with solid targets at irradiances of over 1016 Wcm−2, in the presence of a substantial prepulse has been investigated. High absorption of laser energy is found even at high angles of incidence, with evidence for a resonance absorption peak being found for S, P, and circular polarizations. It is considered that this may be a result of refraction and beam filamentation, which causes loss of distinct polarization. Measurements of hard X-ray emission (∼ 100 keV) confirm a resonance absorption type peak at 45−50°, again for all three cases. Typically, 5−15% of the incident light is back-reflected by stimulated Brillouin scatter, with spatially resolved spectra showing evidence of beam hot-spots at high intensity. The possibility that filamentation and refraction of the beam can explain the lack of polarization dependence in the absorption and hard X-ray emission data is discussed.


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