Electronic spectroscopy of jet-cooled CFCl: Laser-induced fluorescence, dispersed fluorescence, lifetimes, and C–Cl dissociation barrier

2001 ◽  
Vol 115 (24) ◽  
pp. 11118-11130 ◽  
Author(s):  
Joseph S. Guss ◽  
Ondrej Votava ◽  
Scott H. Kable
Keyword(s):  
Electronic Spectroscopy ◽  
Laser Induced Fluorescence ◽  
Fluorescence Lifetimes ◽  
Dispersed Fluorescence ◽  
Dissociation Barrier

The rotationally resolved electronic spectra of several conformers of 1-hexoxy and 1-heptoxy

2004 ◽  
Vol 82 (6) ◽  
pp. 854-866 ◽  
Author(s):  
Lily Zu ◽  
Jinjun Liu ◽  
Sandhya Gopalakrishnan ◽  
Terry A Miller
Keyword(s):  
Atmospheric Chemistry ◽  
Electronic Spectroscopy ◽  
Laser Induced Fluorescence ◽  
Organic Radicals ◽  
Excitation Spectra ◽  
Fluorescence Excitation ◽  
Alkoxy Radicals ◽  
Fluorescence Excitation Spectra ◽  
Quantum Chemistry Calculations ◽  
Experimental Values

Laser-induced fluorescence excitation spectra of five vibronic bands of 1-hexoxy and three bands of 1-heptoxy have been recorded in a jet-cooled environment. Experimental values of rotational constants for both the [Formula: see text] and [Formula: see text] states and components of the spin-rotational tensor for the [Formula: see text] state were obtained by an analysis of the partially resolved rotational structure of the vibronic bands. Comparing these experimental results with quantum chemistry calculations, and using corresponding assignments of smaller alkoxy radicals as a guide, permitted unambiguous conformational assignments for the bands. The extension of similar assignments to larger alkoxy radicals is also discussed. Key words: electronic spectroscopy, organic radicals, combustion, atmospheric chemistry.

Laser-induced fluorescence and dispersed fluorescence spectroscopy of jet-cooled 1-phenylpropargyl radical

2009 ◽  
Vol 130 (14) ◽  
pp. 144313 ◽  
Author(s):  
Neil J. Reilly ◽  
Masakazu Nakajima ◽  
Bligh A. Gibson ◽  
Timothy W. Schmidt ◽  
Scott H. Kable
Keyword(s):  
Fluorescence Spectroscopy ◽  
Laser Induced Fluorescence ◽  
Dispersed Fluorescence
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