Exact Solution of the Mean Spherical Model for Fluids of Hard Spheres with Permanent Electric Dipole Moments

1971 ◽  
Vol 55 (9) ◽  
pp. 4291-4298 ◽  
Author(s):  
M. S. Wertheim
Keyword(s):  
Exact Solution ◽  
Electric Dipole ◽  
Hard Spheres ◽  
Dipole Moments ◽  
Spherical Model ◽  
Electric Dipole Moments ◽  
Mean Spherical Model ◽  
The Mean

Exact solution of the mean spherical model for charged hard spheres in a uniform neutralizing background

1973 ◽  
Vol 58 (10) ◽  
pp. 4171-4174 ◽  
Author(s):  
R. G. Palmer ◽  
J. D. Weeks
Keyword(s):  
Exact Solution ◽  
Hard Spheres ◽  
Spherical Model ◽  
Mean Spherical Model ◽  
The Mean ◽  
Charged Hard Spheres

Quantum theory of solvent effects on electronic spectra: Predictions of the exact solution of the mean spherical model

1983 ◽  
Vol 78 (6) ◽  
pp. 4118-4125 ◽  
Author(s):  
Kenneth S. Schweizer ◽  
David Chandler
Keyword(s):  
Exact Solution ◽  
Quantum Theory ◽  
Solvent Effects ◽  
Electronic Spectra ◽  
Spherical Model ◽  
Mean Spherical Model ◽  
The Mean

Influence of Environment on the Electronic Spectra of Donor-Acceptor-Substituted trans-Stilbenes in Solvent Mixtures

1981 ◽  
Vol 36 (9) ◽  
pp. 999-1001 ◽  
Author(s):  
A. Kawski ◽  
B. Ostrowska ◽  
M. Ston
Keyword(s):  
Excited States ◽  
Electric Dipole ◽  
Fluorescence Spectra ◽  
Dipole Moments ◽  
Solvent Mixtures ◽  
Absorption And Fluorescence Spectra ◽  
Electric Dipole Moments ◽  
Mean Lifetime ◽  
Donor Acceptor ◽  
The Mean

AbstractThe effect of n-heptane and n-butanol mixtures upon the absorption and fluorescence spectra of donor-acceptor-substituted trans-stilbenes is investigated. The electronic-vibration spectra of these compounds depend upon the magnitude of the electric dipole moments in the ground and excited states, upon the relation between the mean lifetime τfw and the time of dielectric relaxation τR, and upon the environment around the solute molecule.

Exact solution of the mean spherical model for simple polar mixtures

1973 ◽  
Vol 59 (8) ◽  
pp. 3971-3980 ◽  
Author(s):  
S. A. Adelman ◽  
J. M. Deutch
Keyword(s):  
Exact Solution ◽  
Spherical Model ◽  
Mean Spherical Model ◽  
The Mean ◽  
Polar Mixtures

Exact solution of the mean spherical model for strong electrolytes in polar solvents

1974 ◽  
Vol 60 (10) ◽  
pp. 3935-3949 ◽  
Author(s):  
S. A. Adelman ◽  
J. M. Deutch
Keyword(s):  
Exact Solution ◽  
Spherical Model ◽  
Polar Solvents ◽  
Mean Spherical Model ◽  
Strong Electrolytes ◽  
The Mean

Electronic States of a Topologically Disordered System: Exact Solution of the Mean Spherical Model for Liquids

1982 ◽  
Vol 49 (15) ◽  
pp. 1100-1103 ◽  
Author(s):  
David Chandler ◽  
Kenneth S. Schweizer ◽  
Peter G. Wolynes
Keyword(s):  
Exact Solution ◽  
Electronic States ◽  
Spherical Model ◽  
Disordered System ◽  
Mean Spherical Model ◽  
The Mean

scholarly journals Exact solution of the mean spherical model for the electric microfield distribution in a plasma

1986 ◽  
Vol 34 (5) ◽  
pp. 4131-4135 ◽  
Author(s):  
F. Lado
Keyword(s):  
Exact Solution ◽  
Spherical Model ◽  
Mean Spherical Model ◽  
The Mean

Dipole moments in excited state. Solvatochromic equations based on different local-field models

1984 ◽  
Vol 49 (7) ◽  
pp. 1680-1694 ◽  
Author(s):  
Bohumír Koutek
Keyword(s):  
Excited State ◽  
Electronic Absorption Spectra ◽  
Dipole Moments ◽  
Spherical Model ◽  
Exponential Model ◽  
Reaction Field ◽  
Solvent Dependence ◽  
Mean Spherical Model ◽  
Order Of Magnitude ◽  
The Mean

Two recent dielectric models, viz. the inverse exponential model of Block and Walker (BW) and the mean spherical model of Wertheim (W), were applied to the conceptually simple solvatochromic theory in the attempt to appreciate their ability to predict excited state dipole moments (μe) on the basis of the solvent dependence of electronic absorption spectra. Validity of the suggested equations was tested by standard methods of statistical analysis, as well as by comparison of the predicted μe values with those obtained independently from electrooptical measurements.All variants, including the original Onsager (O) formulation appear to be acceptable, the correlation coefficient varying from 0.920 to 0.982. However, they predict different μe values the order of magnitude being (for a given solute) invariably (μe)BW > (μe)O > (μe)W. In view of the large uncertainties in the cavity radius a, no unambiguous conclusions can be drawn on the preference of the respective models. Provided that the mean polarizability α is approximated by α = a3/2, the most satisfactory results (mean relative error in μe of about ±6%, R = 0.930-0.960) are obtained by using the reaction field model of Block and Walker.

Exact solution of the mean spherical model for fluids of non-spherical molecules

1975 ◽  
Vol 30 (3) ◽  
pp. 889-898 ◽  
Author(s):  
D.A. MacInnes ◽  
I.E. Farquhar
Keyword(s):  
Exact Solution ◽  
Spherical Model ◽  
Mean Spherical Model ◽  
The Mean

The mean spherical model for charged hard spheres

1975 ◽  
Vol 29 (5) ◽  
pp. 1521-1531 ◽  
Author(s):  
C.W. Outhwaite ◽  
V.C.L. Hutson
Keyword(s):  
Hard Spheres ◽  
Spherical Model ◽  
Mean Spherical Model ◽  
The Mean ◽  
Charged Hard Spheres
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