Total Cross Sections for Ionization and Attachment in Gases by Electron Impact. II. Negative‐Ion Formation

1965 ◽  
Vol 43 (5) ◽  
pp. 1480-1489 ◽  
Author(s):  
Donald Rapp ◽  
Donald D. Briglia
2004 ◽  
Vol 37 (15) ◽  
pp. 3013-3020 ◽  
Author(s):  
S Feil ◽  
K Gluch ◽  
S Matt-Leubner ◽  
P Scheier ◽  
J Limtrakul ◽  
...  

Atoms ◽  
2020 ◽  
Vol 8 (2) ◽  
pp. 17
Author(s):  
Zineb Felfli ◽  
Alfred Z. Msezane

The robust Regge-pole methodology wherein is fully embedded the essential electron-electron correlation effects and the vital core polarization interaction has been used to explore negative ion formation in the large lanthanide Ho, Er, Tm, Yb, Lu, and Hf atoms through the electron elastic total cross sections (TCSs) calculations. These TCSs are characterized generally by dramatically sharp resonances manifesting ground, metastable, and excited negative ion formation during the collisions, Ramsauer-Townsend minima, and shape resonances. The novelty and generality of the Regge-pole approach is in the extraction of the negative ion binding energies (BEs) of complex heavy systems from the calculated electron TCSs. The extracted anionic BEs from the ground state TCSs for Ho, Er, Tm, Yb, Lu, and Hf atoms are 3.51 eV, 3.53 eV, 3.36 eV, 3.49 eV, 4.09 eV and 1.68 eV, respectively. The TCSs are presented and the extracted from the ground; metastable and excited anionic states BEs are compared with the available measured and/or calculated electron affinities. We conclude with a remark on the existing inconsistencies in the meaning of the electron affinity among the various measurements and/or calculations in the investigated atoms and make a recommendation to resolve the ambiguity.


Atoms ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 84
Author(s):  
Alfred Z. Msezane ◽  
Zineb Felfli

The rigorous Regge-pole method is used to investigate negative-ion formation in actinide atoms through electron elastic total cross sections (TCSs) calculation. The TCSs are found to be characterized generally by negative-ion formations, shape resonances and Ramsauer-Townsend(R-T) minima, and they exhibit both atomic and fullerene molecular behavior near the threshold. Additionally, a polarization-induced metastable cross section with a deep R-T minimum is identified near the threshold in the Am, Cm and Bk TCSs, which flips over to a shape resonance appearing very close to the threshold in the TCSs for Es, No and Lr. We attribute these new manifestations to size effects and orbital collapse significantly impacting the polarization interaction. From the TCSs unambiguous and reliable ground, metastable and excited states negative-ion binding energies (BEs) for Am−, Cm−, Bk−, Es−, No− and Lr− anions formed during the collisions are extracted and compared with existing electron affinities (EAs) of the atoms. The novelty of the Regge-pole approach is in the extraction of the negative-ion BEs from the TCSs. We conclude that the existing theoretical EAs of the actinide atoms and the recently measured EA of Th correspond to excited anionic BEs.


2009 ◽  
Vol 194 (4) ◽  
pp. 042038 ◽  
Author(s):  
K N Joshipura ◽  
Sumona Gangopadhyay ◽  
Harshit N Kothari ◽  
Foram A Shelat

2011 ◽  
Vol 85 (12) ◽  
pp. 1717-1720 ◽  
Author(s):  
K. C. Rao ◽  
K. G. Bhushan ◽  
R. Mukund ◽  
S. M. Rodrigues ◽  
S. K. Gupta ◽  
...  

Author(s):  
Zineb Felfli ◽  
Kelvin Suggs ◽  
Nantambu Nicholas ◽  
Alfred Z. Msezane

We first explore negative-ion formation in fullerenes C44, C60, C70, C98, C112, C120, C132 and C136 through low-energy electron elastic scattering total cross sections calculations using our Regge-pole methodology. Water oxidation to peroxide and water synthesis from H2 and O2 are then investigated using the anionic catalysts C44ˉ to C136ˉ. The fundamental mechanism underlying negative-ion catalysis involves hydrogen bond strength-weakening in the transition state. DFT transition state calculations found C60ˉ numerically stable for both water and peroxide synthesis, C100ˉ increases the energy barrier the most and C136ˉ the most effective catalyst in both water synthesis and oxidation to H2O2.


2019 ◽  
Vol 73 (2) ◽  
Author(s):  
Matthieu Génévriez ◽  
Pierre Defrance ◽  
Jozo J. Jureta ◽  
Xavier Urbain

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