Experimental dipole moment function and calculated radiative lifetimes for vibrational transitions in carbon monoxide a 3Π

1975 ◽  
Vol 63 (9) ◽  
pp. 3756 ◽  
Author(s):  
Brian G. Wicke ◽  
William Klemperer
Keyword(s):  
Carbon Monoxide ◽  
Dipole Moment ◽  
Moment Function ◽  
Radiative Lifetimes ◽  
Experimental Dipole Moment ◽  
Vibrational Transitions

Experimental determination of the 1Σ+ state electric dipole moment function of carbon monoxide up to a large internuclear separation

1984 ◽  
Vol 62 (12) ◽  
pp. 1579-1585 ◽  
Author(s):  
C. Chackerian Jr. ◽  
R. Farrenq ◽  
G. Guelachvili ◽  
C. Rossetti ◽  
W. Urban
Keyword(s):  
Carbon Monoxide ◽  
Dipole Moment ◽  
Electric Dipole Moment ◽  
Electric Dipole ◽  
Nonlinear Least Squares ◽  
Moment Function ◽  
Fitting Procedure ◽  
Intensity Information ◽  
Transition Matrix Elements

Experimental intensity information is combined with numerically obtained vibrational wave functions in a nonlinear least-squares fitting procedure to obtain the ground electronic state electric dipole moment function of carbon monoxide valid in the range of nuclear oscillation (0.87–1.91 Å) of about the V = 38th vibrational level. Vibrational transition matrix elements are computed from this function for ΔV = 1, 2, 3 with V ≤ 38.

Mesure des intensités des bandes d'absorption rovibrationnelles 0 → 4 et 0 → 5 de l'acide iodhydrique gazeux

1978 ◽  
Vol 56 (6) ◽  
pp. 727-736 ◽  
Author(s):  
P. Niay ◽  
P. Bernage ◽  
C. Coquant ◽  
R. Houdart
Keyword(s):  
Dipole Moment ◽  
White Cell ◽  
Moment Function ◽  
Resolving Power ◽  
Absorption Bands ◽  
Moment Expansion ◽  
Expansion Series ◽  
Experimental Dipole Moment ◽  
Growth Method ◽  
Lorentz Profile

By using a SISAM spectrometer with a 0.03 cm−1 resolving power we have measured the line-strengths for the 4 ← 0 and 5 ← 0 absorption bands of the HI molecule. The pressure in the White cell was important enough to assume the lines to be described through a Lorentz profile, and we have used the 'curve of growth' method. By using all the available data on the 1 ← 0,2 ← 0, and 3 ← 0 bands, we have calculated the first six coefficients of the dipole moment expansion series. The shape of the experimental dipole moment function shows that the HI bond is primarily covalent.

Infrared Line and Band Strengths and Dipole Moment Function in HCl and DCl

1957 ◽  
Vol 26 (6) ◽  
pp. 1671-1677 ◽  
Author(s):  
William S. Benedict ◽  
Robert Herman ◽  
Gordon E. Moore ◽  
Shirleigh Silverman
Keyword(s):  
Dipole Moment ◽  
Moment Function

MCSCF calculation of the dipole moment function of CO

1981 ◽  
Vol 44 (1) ◽  
pp. 111-123 ◽  
Author(s):  
Hans-Joachim Werner
Keyword(s):  
Dipole Moment ◽  
Moment Function

Notizen: The Dipole Moment Function of HF Molecule Using Morse Potential

1977 ◽  
Vol 32 (8) ◽  
pp. 897-898 ◽  
Author(s):  
Y. K. Chan ◽  
B. S. Rao
Keyword(s):  
Wave Equation ◽  
Dipole Moment ◽  
Potential Function ◽  
Electric Dipole ◽  
Morse Potential ◽  
Moment Function ◽  
Matrix Elements ◽  
The Matrix ◽  
Vibration Rotation ◽  
Experimental Values

Abstract The radial Schrödinger wave equation with Morse potential function is solved for HF molecule. The resulting vibration-rotation eigenfunctions are then used to compute the matrix elements of (r - re)n. These are combined with the experimental values of the electric dipole matrix elements to calculate the dipole moment coefficients, M 1 and M 2.

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