Vibrational energy level statistics of small molecules

1991 ◽  
Vol 94 (5) ◽  
pp. 3293-3301 ◽  
Author(s):  
W. Karrlein
Keyword(s):  
Energy Level ◽  
Small Molecules ◽  
Vibrational Energy ◽  
Vibrational Energy Level ◽  
Level Statistics

scholarly journals A re-examination of the adiabatic correction term for the hydrogen molecule

1976 ◽  
Vol 54 (4) ◽  
pp. 651-656 ◽  
Author(s):  
Huw O. Pritchard ◽  
Lutosław Wolniewicz
Keyword(s):  
Energy Level ◽  
Hydrogen Molecule ◽  
Vibrational Energy ◽  
Correction Term ◽  
Internuclear Separation ◽  
Vibrational Energy Level ◽  
The Difference ◽  
The One

The adiabatic coupling correction term [Formula: see text] has been evaluated by two methods, the one used by Kołos and Wolniewicz in 1964 and the one suggested by Kari, Chan, Hunter, and Pritchard in 1973. The difference between the two procedures for H2 amounts to 0.04 cm−1 and is almost independent of internuclear separation in the range R = 1.0–1.8 a.u. Thus, the method of computing the ΔR-term does not affect the vibrational energy level spacings.

Vibrational Energy Level Calculations

2002 ◽  
Author(s):  
Tucker Carrington
Keyword(s):  
Energy Level ◽  
Vibrational Energy ◽  
Vibrational Energy Level

The Vibrational Energy Level System of the Linear Molecule HCN

1934 ◽  
Vol 45 (4) ◽  
pp. 277-279 ◽  
Author(s):  
Arthur Adel ◽  
E. F. Barker
Keyword(s):  
Energy Level ◽  
Vibrational Energy ◽  
Linear Molecule ◽  
Level System ◽  
Vibrational Energy Level

Initial Vibrational Energy Level Populations Resulting from the Reaction H+F2 as Studied by Infrared Chemiluminescence

1970 ◽  
Vol 53 (11) ◽  
pp. 4396-4397 ◽  
Author(s):  
Neville Jonathan ◽  
C. M. Melliar‐Smith ◽  
David H. Slater
Keyword(s):  
Energy Level ◽  
Vibrational Energy ◽  
Vibrational Energy Level

The Master Equation for the Dissociation of a Dilute Diatomic Gas. XI. Vibrational Freezing in a Nozzle Flow

1974 ◽  
Vol 52 (6) ◽  
pp. 939-941 ◽  
Author(s):  
Nabil I. Labib ◽  
Huw O. Pritchard
Keyword(s):  
Relaxation Time ◽  
Energy Level ◽  
Master Equation ◽  
Rate Constant ◽  
Ground State ◽  
Vibrational Relaxation ◽  
Vibrational Energy ◽  
Nozzle Flow ◽  
Vibrational Energy Level ◽  
Diatomic Gas

A previously reported calculation on a model expansion in a nozzle flow is extended to the point where the whole vibrational energy "freezes" and the behavior of the vibrational relaxation time is examined. Starting with the high levels, each individual vibrational energy level becomes decoupled from the ground state in sequence, down to and including υ = 1; under these conditions, all measures of the vibrational relaxation time fail, but perhaps surprisingly the rate constant for recombination remains well defined.

Vibrational Energy Level Population in Optically Pumped AgCl Vapor

1967 ◽  
Vol 6 (9) ◽  
pp. 1545
Author(s):  
L. Allen ◽  
D. G. C. Jones
Keyword(s):  
Energy Level ◽  
Vibrational Energy ◽  
Level Population ◽  
Optically Pumped ◽  
Vibrational Energy Level
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