Branching ratios and bond dissociation energies from the excimer laser photolysis of group 6 metal carbonyls

1991 ◽  
Vol 94 (8) ◽  
pp. 5471-5480 ◽  
Author(s):  
D. M. Rayner ◽  
Y. Ishikawa ◽  
C. E. Brown ◽  
P. A. Hackett
Keyword(s):  
Excimer Laser ◽  
Branching Ratios ◽  
Laser Photolysis ◽  
Bond Dissociation Energies ◽  
Metal Carbonyls ◽  
Bond Dissociation ◽  
Dissociation Energies ◽  
Group 6

Electron-impact study of some binary metal carbonyls

1967 ◽  
Vol 45 (6) ◽  
pp. 641-648 ◽  
Author(s):  
D. R. Bidinosti ◽  
N. S. McIntyre
Keyword(s):  
Mass Spectra ◽  
Major Ions ◽  
Heat Of Formation ◽  
Bond Dissociation Energies ◽  
Metal Carbonyls ◽  
Kcal Mole ◽  
Carbon Bond ◽  
Bond Dissociation ◽  
Dissociation Energies ◽  
The Mean

The mass spectra and appearance potentials for the major ions from Ni(CO)4, Fe(CO)5, Cr(CO)6, Mo(CO)6, W(CO)6, and V(CO)6 have been measured. Heats of formation have been calculated for 39 ions of the type M(CO)n+, where M = Ni, Fe, Cr, Mo, W, and V. The mean metal–carbon bond dissociation energies have been calculated for both the neutral molecules and the parent ions. From a comparison with the available thermochemical data for the neutral molecules it is concluded that the mean vanadium–carbon bond dissociation energy is 28 kcal/mole and the heat of formation of V(CO)6 vapor is − 204 kcal/mole.

Excimer laser photolysis of Group 6 metal carbonyls in the gas phase

1990 ◽  
Vol 94 (6) ◽  
pp. 2404-2413 ◽  
Author(s):  
Yoichi. Ishikawa ◽  
Carl E. Brown ◽  
Peter A. Hackett ◽  
David M. Rayner
Keyword(s):  
Gas Phase ◽  
Excimer Laser ◽  
Laser Photolysis ◽  
Metal Carbonyls ◽  
Group 6

ChemInform Abstract: Excimer Laser Photolysis of Group 6 Metal Carbonyls in the Gas Phase.

ChemInform ◽  
1990 ◽  
Vol 21 (27) ◽  
Author(s):  
Y. ISHIKAWA ◽  
C. E. BROWN ◽  
P. A. HACKETT ◽  
D. M. RAYNER
Keyword(s):  
Gas Phase ◽  
Excimer Laser ◽  
Laser Photolysis ◽  
Metal Carbonyls ◽  
Group 6

scholarly journals Experimental bond dissociation energies of benzylpyridinium thermometer ions determined by threshold-CID and RRKM modeling

2017 ◽  
Vol 417 ◽  
pp. 69-75 ◽  
Author(s):  
David Gatineau ◽  
Antony Memboeuf ◽  
Anne Milet ◽  
Richard B. Cole ◽  
Héloïse Dossmann ◽  
...  
Keyword(s):  
Bond Dissociation Energies ◽  
Bond Dissociation ◽  
Dissociation Energies ◽  
Thermometer Ions
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