Structural and ionic conductivity behavior in hydroxypropylmethylcellulose (HPMC) polymer films complexed with sodium iodide (NaI)

2013 ◽  
Author(s):  
N. Sandhya Rani ◽  
J. Sannappa ◽  
T. Demappa ◽  
Mahadevaiah
Keyword(s):  
Ionic Conductivity ◽  
Polymer Films ◽  
Sodium Iodide ◽  
Conductivity Behavior

Temperature glass and conductivity behavior of epoxy deproteinized natural rubber in ternary blend of EDPNR/PMMA/LiCF3SO3

2021 ◽  
pp. 147776062110420
Author(s):  
Trịnh Thị Hang ◽  
I Putu Mahendra ◽  
Tran Manh Thang ◽  
Seiichi Kawahara ◽  
Phan Trung Nghia
Keyword(s):  
Ionic Conductivity ◽  
Natural Rubber ◽  
Lithium Salt ◽  
Ternary Blend ◽  
Ternary Blends ◽  
Binary Blends ◽  
Lithium Trifluoromethanesulfonate ◽  
The Right ◽  
Deproteinized Natural Rubber ◽  
Conductivity Behavior

The temperature glass behavior of epoxy deproteinized natural rubber/polymethylmethacrylate/lithium trifluoromethanesulfonate (EDPNR/PMMA/LiCF3SO3) and the conductivity behavior of EDPNR in the ternary blends were studied by DSC and multichannel potentiostat. The DSC result revealed the temperature glass of the EDPNR was shifted to the right with the increase of lithium salt amount in these binary blends composition. However, in the ternary blends of EDPNR/PMMA/LiCF3SO3 the temperature glass revealed the miscibility of these ternary blends. Two different temperature glass values were obtained when the ratio of EDPNR in EDPNR/PMMA was less than 80 wt.%. The ionic conductivity of EDPNR could be improved by increasing the amount of lithium salt up to 35 wt.%, after this amount the ionic conductivity of EDPNR was significantly decreased. While in the ternary blends, the highest ionic conductivity value was found at the ratio 80/20 of EDPNR/PMMA. Furthermore, the factors influencing the temperature glass and conductivity behavior of EDPNR were systematically studied in this work. The results demonstrated an intimate correlation between temperature glass and conductivity behavior of EDPNR.

Tunability of structure from ordered to disordered and its impact on ionic conductivity behavior in the Nd2−yHoyZr2O7 (0.0 ≤ y ≤ 2.0) system

RSC Advances ◽  
2012 ◽  
Vol 2 (22) ◽  
pp. 8341 ◽  
Author(s):  
Farheen N. Sayed ◽  
Dheeraj Jain ◽  
B.P. Mandal ◽  
C. G. S. Pillai ◽  
A. K. Tyagi
Keyword(s):  
Ionic Conductivity ◽  
Conductivity Behavior

Conformational, thermal, and ionic conductivity behavior of PEO in PEO/PMMA miscible blend: Investigating the effect of lithium salt

2012 ◽  
Vol 129 (4) ◽  
pp. 1868-1874 ◽  
Author(s):  
Mahdi Ghelichi ◽  
Nader Taheri Qazvini ◽  
Seyed Hassan Jafari ◽  
Hossein Ali Khonakdar ◽  
Yaser Farajollahi ◽  
...  
Keyword(s):  
Ionic Conductivity ◽  
Lithium Salt ◽  
Miscible Blend ◽  
Conductivity Behavior

Testing the Applicability of an Expression for the Non-Arrhenius Ionic Conductivity in Solid Electrolytes

2010 ◽  
Vol 123-125 ◽  
pp. 1103-1106 ◽  
Author(s):  
Takaki Indoh ◽  
Masaru Aniya
Keyword(s):  
Ionic Conductivity ◽  
Solid Electrolytes ◽  
Ionic Conduction ◽  
Present Report ◽  
Physical Factor ◽  
Arrhenius Behavior ◽  
Conduction Behavior ◽  
Mixed Ionic Electronic Conductors ◽  
Electronic Conductors ◽  
Conductivity Behavior

In a previous study, we have proposed a model that describes the non-Arrhenius ionic conduction behavior in superionic glasses. In the present report, the model is applied to analyze the conductivity behavior of a wide variety of solid electrolytes that include crystals, glasses, polymers, composites and mixed ionic-electronic conductors. From the analysis of the model, the physical factor responsible for the non-Arrhenius behavior has been extracted and discussed.

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