Influence of Al2O3 on the ionic conductivity of plasticized PVC-PEG blend polymer electrolytes

2016 ◽  
Author(s):  
D. Ravindran ◽  
P. Vickraman
2000 ◽  
Vol 89 (1) ◽  
pp. 80-87 ◽  
Author(s):  
A.Manuel Stephan ◽  
T.Prem Kumar ◽  
N.G Renganathan ◽  
S Pitchumani ◽  
R Thirunakaran ◽  
...  

Ionics ◽  
2001 ◽  
Vol 7 (1-2) ◽  
pp. 44-52 ◽  
Author(s):  
S. Kalyanasundaram ◽  
A. Gopalan ◽  
N. Muniyandi ◽  
N. G. Renganathan ◽  
Y. Saito ◽  
...  

This is a novel approach to get polyblend films with improved properties such as ionic conductivity and dielectric strength. Different ratios of PEG (5%, 10%, 15%, 20%, 25%, 30%) are added with optimized PVA: PVP ratio. PVA: PVP: PEG based BPEs are prepared by using solution casting method. The polymer PEG act as a plasticizer and chemically stable in air.The prepared electrolytes are characterized by XRD, FTIR and ionic conductivity studies. The XRD analysis shows amorphous nature of the polyblend electrolytes. Dielectric analysis is carried out for the BPEs. The higher conductivity is obtained for 20% PEG added polyblend electrolytes and it is 9.0x10-9 S/Cm. Thus, PVA: PVP: PEG (40:40:20) system is confirmed as optimized one for further studies to enhance the ionic conductivity


2018 ◽  
Vol 2018 ◽  
pp. 1-11 ◽  
Author(s):  
Sk. Shahenoor Basha ◽  
M. C. Rao

Blend polymer electrolytes were prepared with different wt% compositions of [PVA/PVP-MgCl2·6H2O] : x% using solution cast technique. Structural, morphological, vibrational, thermal, and ionic conductivity and electrochemical properties were studied on the prepared polymer films. XRD revealed the crystalline nature of the polymer electrolyte films. The morphology and the degree of roughness of the prepared films were analyzed by SEM. FTIR and Raman studies confirmed the chemical complex nature of the ligands, interlinking bond formation between the blend polymers and the dopant salt. The glass transition temperature (Tg) of polymer electrolytes was confirmed by DSC studies. Ionic conductivity measurements were carried out on the prepared films in the frequency ranging between 5000 Hz and 50000 KHz and found to be maximum (2.42 × 10−4 S/cm) for the prepared film with wt% composition 35PVA/35PVP : 30MgCl2·6H2O at room temperature. The electrochemical studies were also performed on the prepared films. The galvanostatic charge/discharge performance was carried out from 2.9 to 4.4 V for the configuration Mg+/(PVA/PVP + MgCl2·6H2O)/(I2 + C + electrolyte).


Ionics ◽  
2007 ◽  
Vol 14 (2) ◽  
pp. 149-155 ◽  
Author(s):  
S. Rajendran ◽  
Ravi Shanker Babu ◽  
P. Sivakumar

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