scholarly journals An interplay of excluded-volume and polymer–(co)solvent attractive interactions regulates polymer collapse in mixed solvents

2021 ◽  
Vol 154 (13) ◽  
pp. 134903
Author(s):  
Swaminath Bharadwaj ◽  
Divya Nayar ◽  
Cahit Dalgicdir ◽  
Nico F. A. van der Vegt
Keyword(s):  
Mixed Solvents ◽  
Excluded Volume ◽  
Polymer Collapse

Electrostatic and Excluded Volume Effects on the Transport of Electrolytes in Poly(ethylene glycol)−Water “Mixed Solvents”

2003 ◽  
Vol 107 (44) ◽  
pp. 12363-12369 ◽  
Author(s):  
Fabio Capuano ◽  
Alessandro Vergara ◽  
Luigi Paduano ◽  
Onofrio Annunziata ◽  
Roberto Sartorio
Keyword(s):  
Ethylene Glycol ◽  
Mixed Solvents ◽  
Excluded Volume ◽  
Poly Ethylene Glycol ◽  
Excluded Volume Effects ◽  
Poly Ethylene ◽  
Volume Effects

A Field Theory for Polymeric Networks with Excluded Volume

1995 ◽  
Vol 5 (10) ◽  
pp. 1241-1246 ◽  
Author(s):  
Thomas A. Vilgis ◽  
Michael P. Solf
Keyword(s):  
Field Theory ◽  
Excluded Volume ◽  
Polymeric Networks

Self-avoiding-self-attracting model of polymer collapse and adsorption

1991 ◽  
Vol 1 (3) ◽  
pp. 397-419 ◽  
Author(s):  
S. Cattarinussi ◽  
G. Jug
Keyword(s):  
Polymer Collapse

The Equivalent Conductance of Electrolytes in Mixed Solvents

1958 ◽  
Vol 17 (5_6) ◽  
pp. 300-314 ◽  
Author(s):  
Rayburn Whorton ◽  
Edward S. Amis
Keyword(s):  
Mixed Solvents ◽  
Equivalent Conductance

A description of effect of composition of mixed binary solvents on processes in solutions

1988 ◽  
Vol 53 (4) ◽  
pp. 671-685 ◽  
Author(s):  
Oldřich Pytela ◽  
Miroslav Ludwig
Keyword(s):  
Gibbs Energy ◽  
Mixed Solvents ◽  
Theoretical Description ◽  
Energy Change ◽  
Binary Solvents ◽  
Gibbs Energy Change ◽  
Order Model ◽  
Significant Difference

A theoretical description of the effect of changed composition of mixed solvents on processes in solutions has been suggested on the basis of the proportionality between the Gibbs energy change of the process and that of the solvent due to the transition from pure components to the mixture. The additional Gibbs energy has been expressed by means of the so-called classical functions by Margules, van Laar-Wohl, and van Laar-Null. The application to 115 various processes (pK, IR, UV-VIS, NMR, log k, and others) has confirmed that the theoretical presumptions are justified, the most suitable being Margules' 4th order model which shows a statistically significant difference from the models of lower orders.

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