The chemistry of Lauren-1-ene. III. Synthesis and properties of laurenane and 1βH-Lamenane

1981 ◽  
Vol 34 (6) ◽  
pp. 1303 ◽  
Author(s):  
PJ Eaton ◽  
DR Lauren ◽  
AW O'Conner ◽  
RT Weavers
Keyword(s):  
Long Range ◽  
Substituent Effects ◽  
Conformational Mobility ◽  
Saturated Hydrocarbons ◽  
Lanthanide Shift Reagents ◽  
Shift Reagents

The saturated hydrocarbons laurenane (3) and 1βH-laurenane (4) have been synthesized. Assignments of their 13C n.m.r. and 1H n.m.r. spectra are reported and used, with the aid of lanthanide shift reagents, to investigate conformational mobility of these substituted fenestranes. Some examples of long-range 13C n.m.r. substituent effects of the ε and ζ types have been noted.

Interaction of lanthanide shift reagents with alkyltosylates of heterocyclic bases and tosylates of cyanine dyes

1989 ◽  
Vol 25 (2) ◽  
pp. 191-195
Author(s):  
I. V. Komarov ◽  
A. V. Turov ◽  
N. N. Romanov ◽  
M. Yu. Kornilov
Keyword(s):  
Cyanine Dyes ◽  
Lanthanide Shift Reagents ◽  
Shift Reagents ◽  
Heterocyclic Bases
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