Acetal Formation Facilitated in 2-Hydroxyaryl Aldehydes by Intramolecular Acyl Group Transfer
Keyword(s):
Convenient preparations of synthetically useful acetals, a dithioacetal and an oxathiolan from the 2-acyl derivatives of 2-hydroxyaryl aldehydes under basic conditions are described. The mildness of the reaction conditions is illustrated by the formation of an ethoxycarbonyl -substituted dioxolan . The reaction is dependent upon an intramolecular acetyl group transfer and the mechanism of the reaction is discussed. Some broader implications of this type of acyl transfer are discussed.
2016 ◽
Vol 12
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pp. 2343-2350
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1985 ◽
Vol 50
(3)
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pp. 766-778
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1956 ◽
Vol 21
(6)
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pp. 1500-1512
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1965 ◽
Vol 30
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pp. 940-951
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1969 ◽
Vol 34
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pp. 3325-3335
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2005 ◽
Vol 70
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pp. 2075-2085
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