Crossed Aldol Reactions of Dioxolans

The crossed aldol reactions of some cyclohexyl and cyclohexenyl dioxolans with the silyl enol ether of cyclohexanone have, in general, been shown to result in directed opening of the acetal. However, only limited stereoselectivity results at the termini of the new carbon-carbon bond.

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Carbon-carbon bond formation in reactions of PhIO.cntdot.HBF4-silyl enol ether adduct with alkenes or silyl enol ethers

The Journal of Organic Chemistry ◽

10.1021/jo00272a028 ◽

1989 ◽

Vol 54 (11) ◽

pp. 2605-2608 ◽

Cited By ~ 52

Author(s):

V. V. Zhdankin ◽

M. Mullikin ◽

Rik Tykwinski ◽

Bruce Berglund ◽

Ronald Caple ◽

...

Keyword(s):

Bond Formation ◽

Enol Ether ◽

Enol Ethers ◽

Carbon Bond ◽

Silyl Enol Ethers ◽

Carbon Carbon Bond ◽

Silyl Enol Ether

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ChemInform Abstract: Reaction of PhIO·HBF4/Silyl Enol Ether Adduct with Olefins as General Approach to Carbon-Carbon Bond Formation in Adε Reactions Using Hypervalent Iodine Reagents.

ChemInform ◽

10.1002/chin.198905148 ◽

1989 ◽

Vol 20 (5) ◽

Author(s):

V. V. ZHDANKIN ◽

R. TYKWINSKI ◽

R. CAPLE ◽

B. BERGLUND ◽

A. S. KOZ'MIN ◽

...

Keyword(s):

Bond Formation ◽

Hypervalent Iodine ◽

Enol Ether ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Silyl Enol Ether

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Reaction of phIO·HBF4/silyl enol ether adduct with olefins as general approach to carbon—carbon bond formation in AdE reactions using hypervalent iodine reagents

Tetrahedron Letters ◽

10.1016/s0040-4039(00)82158-9 ◽

1988 ◽

Vol 29 (30) ◽

pp. 3703-3704 ◽

Cited By ~ 31

Author(s):

Viktor V. Zhdankin ◽

Rik Tykwinski ◽

Ronald Caple ◽

Bruce Berglund ◽

Anatoly S. Koz'min ◽

...

Keyword(s):

Bond Formation ◽

Hypervalent Iodine ◽

Enol Ether ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Silyl Enol Ether

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ChemInform Abstract: Carbon-Carbon Bond Formation in Reactions of PhIO·HBF4/Silyl Enol Ether Adduct with Alkenes or Silyl Enol Ethers.

ChemInform ◽

10.1002/chin.198947161 ◽

1989 ◽

Vol 20 (47) ◽

Author(s):

V. V. ZHDANKIN ◽

M. MULLIKIN ◽

R. TYKWINSKI ◽

B. BERGLUND ◽

R. CAPLE ◽

...

Keyword(s):

Bond Formation ◽

Enol Ether ◽

Enol Ethers ◽

Carbon Bond ◽

Silyl Enol Ethers ◽

Carbon Carbon Bond ◽

Silyl Enol Ether

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New Application of Solid Acid to Carbon–Carbon Bond Formation Reactions: Clay Montmorillonite-Catalyzed Aldol Reactions of Silyl Enol Ethers with Aldehydes and Acetals

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.61.1237 ◽

1988 ◽

Vol 61 (4) ◽

pp. 1237-1245 ◽

Cited By ~ 63

Author(s):

Motomitsu Kawai ◽

Makoto Onaka ◽

Yusuke Izumi

Keyword(s):

Solid Acid ◽

Bond Formation ◽

Aldol Reactions ◽

Enol Ethers ◽

Carbon Bond ◽

Silyl Enol Ethers ◽

Carbon Carbon Bond ◽

Bond Formation Reactions

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Asymmetric Carbon-Carbon Bond-Forming Reactions: Asymmetric Aldol Reactions-Discovery and Development

Catalytic Asymmetric Synthesis ◽

10.1002/0471721506.ch15 ◽

2005 ◽

pp. 493-512 ◽

Cited By ~ 1

Author(s):

Masaya Sawamura ◽

Yoshihiko Ito

Keyword(s):

Aldol Reactions ◽

Asymmetric Aldol ◽

Carbon Bond ◽

Bond Forming ◽

Carbon Carbon Bond ◽

Bond Forming Reactions ◽

Asymmetric Carbon

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Desymmetrisation of a Centrosymmetric Molecule by Carbon–Carbon Bond Formation: Asymmetric Aldol Reactions of a Centrosymmetric Dialdehyde

Chemistry - A European Journal ◽

10.1002/chem.200700277 ◽

2007 ◽

Vol 13 (20) ◽

pp. 5857-5861 ◽

Cited By ~ 11

Author(s):

Karen Dodd ◽

Daniel Morton ◽

Stephen Worden ◽

Robert Narquizian ◽

Adam Nelson

Keyword(s):

Bond Formation ◽

Aldol Reactions ◽

Asymmetric Aldol ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Centrosymmetric Molecule

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ChemInform Abstract: Amino Acid Catalyzed Direct Asymmetric Aldol Reactions: A Bioorganic Approach to Catalytic Asymmetric Carbon-Carbon Bond-Forming Reactions.

ChemInform ◽

10.1002/chin.200138028 ◽

2010 ◽

Vol 32 (38) ◽

pp. no-no

Author(s):

Kandasamy Sakthivel ◽

Wolfgang Notz ◽

Tommy Bui ◽

Carlos F. Barbas III

Keyword(s):

Amino Acid ◽

Aldol Reactions ◽

Asymmetric Aldol ◽

Carbon Bond ◽

Bond Forming ◽

Carbon Carbon Bond ◽

Bond Forming Reactions ◽

Acid Catalyzed ◽

Catalytic Asymmetric ◽

Asymmetric Carbon

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ChemInform Abstract: New Application of Solid Acid to Carbon-Carbon Bond Formation Reactions: Clay Montmorillonite-Catalyzed Aldol Reactions of Silyl Enol Ethers with Aldehydes and Acetals.

ChemInform ◽

10.1002/chin.198835234 ◽

1988 ◽

Vol 19 (35) ◽

Author(s):

M. KAWAI ◽

M. ONAKA ◽

Y. IZUMI

Keyword(s):

Solid Acid ◽

Bond Formation ◽

Aldol Reactions ◽

Enol Ethers ◽

Carbon Bond ◽

Silyl Enol Ethers ◽

Carbon Carbon Bond ◽

Bond Formation Reactions

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An overview of Zn-catalyzed enantioselective aldol type C–C bond formation

RSC Advances ◽

10.1039/c5ra10102f ◽

2015 ◽

Vol 5 (76) ◽

pp. 62179-62193 ◽

Cited By ~ 24

Author(s):

Amrutha P. Thankachan ◽

S. Asha ◽

K. S. Sindhu ◽

Gopinathan Anilkumar

Keyword(s):

Bond Formation ◽

Aldol Reactions ◽

Carbon Bond ◽

Carbon Carbon Bond ◽

Wide Range ◽

Efficient Route ◽

Type C

Enantioselective zinc-catalyzed aldol reactions provide an efficient route for the construction of a wide range of carbon–carbon bond-formation, which are described here.

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