Fourier transform emission spectroscopy of the second negative (A2Piu - X2Pig) system of the O+2 ion

1997 ◽  
Vol 91 (6) ◽  
pp. 1059-1074 ◽  
Author(s):  
By C. V. V. PRASAD ◽  
D. LACOMBE ◽  
K. WALKER ◽  
W. KONG ◽  
P. BERNATH ◽  
...  
1990 ◽  
Vol 92 (4) ◽  
pp. 2244-2247 ◽  
Author(s):  
N. Oliphant ◽  
A. Lee ◽  
P. F. Bernath ◽  
C. R. Brazier

1987 ◽  
Vol 98 ◽  
Author(s):  
Brent A. Detering ◽  
James A. Batdorf ◽  
Chien M. Wai

ABSTRACTPlasma flow field temperatures are determined in a nontransferred arc plasma using emission spectroscopy. This technique is then utilized to identify thermal decomposition and reduction products produced in the plasma plume when metal oxide particles are injected into the plasma arc. The processed particles are then studied using AAS, SEM, EDS and XRD to characterize the chemical changes that have occurred in the particles. A Fourier transform method is used to study changes in particle morphology.


1996 ◽  
Vol 175 (1) ◽  
pp. 1-6 ◽  
Author(s):  
R.S. Ram ◽  
P.F. Bernath ◽  
S.P. Davis

2018 ◽  
Vol 616 ◽  
pp. A150 ◽  
Author(s):  
M. Ferus ◽  
V. Laitl ◽  
A. Knizek ◽  
P. Kubelík ◽  
J. Sponer ◽  
...  

Time-resolved Fourier transform infrared emission spectroscopy, Fourier transform absorption infrared spectroscopy, and high-resolution UV–ViS emission spectroscopy have been used to characterize the chemistry of isocyanic acid (HNCO) under glow discharge conditions in planetary atmospheres. HNCO mixtures (i.e., composed of di-hydrogen or ammonia) have been investigated in order to unveil the possible reaction pathways leading to the synthesis of the key prebiotic molecule formamide (HCONH2), upon planetary atmospheres containing isocyanic acid in presence of di-hydrogen and, separately, of ammonia. In addition, ab initio molecular dynamics simulations coupled with a modern metadynamics technique have been performed in order to identify the most likely chemical pathways connecting HNCO to formamide. It turned out that the direct hydrogenation of HNCO is thermodynamically favored. Incidentally, the experimental results – supplied by a simplified kinetic model – also proved the favorability of the reaction HNCO + H2→ HCONH2which, moreover, spontaneously takes place in unbiased ab initio molecular dynamics simulations carried out under the effect of intense electric fields.


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