Excess Volumes and Excess Isentropic Compressibility of Binary Mixtures of N, N-Dimethyl for mamide with n-Alcohols at 303.15 K

1985 ◽  
Vol 15 (2) ◽  
pp. 147-154 ◽  
Author(s):  
K. Purnachandra Rao ◽  
K. S. Reddy
1979 ◽  
Vol 32 (8) ◽  
pp. 1649 ◽  
Author(s):  
M Sreenivasulu ◽  
PR Naidu

Excess volumes and isentropic compressibilities for the binary mixtures of cyclohexanone, cylopentanone and 2-methylcyclohexanone with butylamine were determined at 303�15 and 313�15 K. Excess volumes of the three mixtures are negative over the whole range of compositions at both the temperatures. Deviations in isentropic compressibility are also negative in all the three mixtures. The results are ascribed to strong hydrogen bonding between unlike molecules. The results also suggest that cyclization decreases both √E and the deviation in isentropic compressibility.


1979 ◽  
Vol 32 (3) ◽  
pp. 687 ◽  
Author(s):  
KS Reddy ◽  
PR Naidu

Excess volumes and isentropic compressibilities for the binary mixtures of propan-1-ol, butan-1-ol, pentan-1-ol, hexan-1-ol with isobutyl methyl ketone were determined at 303.15 and 313.15 K. Excess volumes of the four mixtures are negative over the whole range of compositions at both the temperatures. Deviations in isentropic compressibility are also negative in all cases, except for propan-1-ol + isobutyl methyl ketone. In this system, the deviation in isentropic compressibility shows an inversion in sign at 303.15 K.


1976 ◽  
Vol 54 (16) ◽  
pp. 2676-2677 ◽  
Author(s):  
Kalluru S. Reddy ◽  
Murari Venkata P. Rao ◽  
Puligundla R. Naidu

Excess volumes of mixtures of 1-propanol +, 1-butanol +, 1-pentanol +, and 1-hexanol + diethylketone have been measured at 303.15 and 313.15 K. Of the four mixtures included here 1-propanol + diethylketone shows an inversion in sign in VE at 313.15 K. VE becomes more positive with increase in temperature.


1986 ◽  
Vol 15 (5) ◽  
pp. 433-438 ◽  
Author(s):  
J. Ortega ◽  
M. I. Paz-Andrade ◽  
E. Rodriguez-N��ez ◽  
F. Sarmiento

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