Mixed Ligand Complexes of Chromium(III), Manganese(III), Iron(III) And Cobalt(III) With Dipicolinic Acid and Some Monobasic Bidentate Nitrogen, Oxygen Donor Ligands

Author(s):  
S. K. Sengupta ◽  
S. K. Sahni ◽  
R. N. Kapoor
2019 ◽  
Vol 13 (1) ◽  
pp. 23-32
Author(s):  
Abhishek Srivastava ◽  
◽  
Neetu Srivastava ◽  
Umesh NathTripathi ◽  
Afshan Siddiqui ◽  
...  

2021 ◽  
Vol 35 (1) ◽  
pp. 61-76
Author(s):  
A. Srivastava ◽  
N. Srivastava ◽  
U. N. Tripathi

A new route to synthesize nano-sized Ti(IV) mixed ligand complexes have been investigated by the reaction of titanium(IV) chloride with ammonium salts of dithiophosphate and 3(2'-hydroxyphenyl)-5-(4-substituted phenyl) pyrazolines. The resultant complex is then treated with H2S gas to get sulfur bridged dimer of Ti(IV) complex, a precursor of TiS2. The morphology of the complexes was studied by employing XRD which shows that all the complexes are amorphous solid. Molecular weight measurements, elemental analysis in conjugation with spectroscopic (IR, 1H NMR, 13C NMR and 31P NMR) studies revealed the dimeric nature of the complexes in which pyrazoline and dithiophosphate are bidentate. Scanning electron microscopic image and XRD indicate that the particles are in the nano range (50 nm). Putting all the facts together, coordination number six is proposed for titanium with octahedral geometry.                     KEY WORDS: Titanium(IV), Dithiophosphate, Pyrazoline, Nano-sized, Sol-gel, Mixed ligand complexes   Bull. Chem. Soc. Ethiop. 2021, 35(1), 61-76. DOI: https://dx.doi.org/10.4314/bcse.v35i1.5


2020 ◽  
pp. 129632
Author(s):  
Ginikachukwu Grace Nnabuike ◽  
Sukanta Mondal ◽  
Sunita Salunke-Gawali ◽  
Archana S. Patil ◽  
Ray J. Butcher ◽  
...  

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