Fatigue and collapse of cyclically bent strip of amorphous solid

Fatigue caused by cyclic bending of a piece of material, resulting in its mechanical failure, is a phenomenon that had been studied for ages by engineers and physicists alike. In this Letter we study such fatigue in a strip of athermal amorphous solid. On the basis of atomistic simulations we conclude that the crucial quantity to focus on is the accumulated damage. Al- though this quantity exhibits large sample-to-sample fluctuations, its dependence on the loading determines the statistics of the number of cycles to failure. Thus we can provide a scaling theory for the Wo ̈hler plots of mean number of cycles for failure as a function of the loading amplitude.

Average density of states of amorphous Hamiltonians: role of phonon mediated coupling of nano-clusters

Based on a description of an amorphous solid as a collection of coupled nanosize molecular clusters referred as basic blocks, we analyse the statistical properties of its Hamiltonian. The information is then used to derive the ensemble averaged density of the vibrational states (nonphonon) which turns out to be a Gaussian in the bulk of the spectrum and an Airy function in the low frequency regime. A comparison with experimental data for five glasses confirms validity of our theoretical predictions.

Mechanochemistry in Portugal—A Step towards Sustainable Chemical Synthesis

In Portugal, publications with mechanochemical methods date back to 2009, with the report on mechanochemical strategies for the synthesis of metallopharmaceuticals. Since then, mechanochemical applications have grown in Portugal, spanning several fields, mainly crystal engineering and supramolecular chemistry, catalysis, and organic and inorganic chemistry. The area with the most increased development is the synthesis of multicomponent crystal forms, with several groups synthesizing solvates, salts, and cocrystals in which the main objective was to improve physical properties of the active pharmaceutical ingredients. Recently, non-crystalline materials, such as ionic liquids and amorphous solid dispersions, have also been studied using mechanochemical methods. An area that is in expansion is the use of mechanochemical synthesis of bioinspired metal-organic frameworks with an emphasis in antibiotic coordination frameworks. The use of mechanochemistry for catalysis and organic and inorganic synthesis has also grown due to the synthetic advantages, ease of synthesis, scalability, sustainability, and, in the majority of cases, the superior properties of the synthesized materials. It can be easily concluded that mechanochemistry is expanding in Portugal in diverse research areas.