(Liquid +Liquid) Equilibrium for Ternary Systems Containing of an Ionic Liquid, n-Hexane and an Organic Compound Involved in the Kinetic Resolution ofrac-2-Pentanol

2012 ◽  
Vol 47 (2) ◽  
pp. 300-311 ◽  
Author(s):  
A. P. de los Ríos ◽  
F. J. Hernández Fernández ◽  
D. Gómez ◽  
M. Rubio ◽  
G. Víllora
Keyword(s):  
Ionic Liquid ◽  
Organic Compound ◽  
Kinetic Resolution ◽  
Ternary Systems ◽  
Liquid Equilibrium

Liquid–Liquid Equilibrium Data for Ternary Systems Containing Alkanes (n-Pentane, n-Hexane, n-Heptane, and n-Octane) + Alcohol (Methanol and Ethanol) + Protic Ionic Liquid (2-HEAF)

2019 ◽  
Vol 64 (12) ◽  
pp. 5167-5173
Author(s):  
Regiane Silva Pinheiro ◽  
Francisca Maria Rodrigues Mesquita ◽  
Matheus Salmito Rodrigues Ponte ◽  
Laís Coelho Lopes ◽  
Filipe Xavier Feitosa ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ternary Systems ◽  
Liquid Equilibrium ◽  
Protic Ionic Liquid ◽  
Equilibrium Data

Solid-Liquid Equilibrium in the Systems with an Ionic Liquid

2008 ◽  
Vol 73 (5) ◽  
pp. 657-664 ◽  
Author(s):  
Zuzana Sedláková ◽  
Hélène Sauton ◽  
Vladimír Hynek ◽  
Ivona Malijevská
Keyword(s):  
Ionic Liquid ◽  
Acetic Acid ◽  
Binary System ◽  
Propionic Acid ◽  
Solid Phase ◽  
Ternary Systems ◽  
Liquid Equilibrium ◽  
Solid Compound ◽  
Active Interest ◽  
Solid Liquid

An active interest in ionic liquids has grown over the last years. This relatively new class of solvents appears to be potentially useful as a "greener" alternative to volatile organic compounds. This work was aimed at studying the effect of addition of the ionic liquid 1-butyl-3-methylimidazolium chloride to two systems (acetic acid (1)-formamide (2) and propionic acid (1)-formamide (2)) on formation of a compound in the solid phase. In previous work, the presence of a solid compound with a formula (CH3COOH)2·HCONH2 was investigated in the binary system acetic acid (1)-formamide (2) and a stable solid compound with a different formula CH3CH2COOH·(HCONH2)2 was found in the binary system propionic acid (1)-formamide (2). In both cases the compound formation is attributed to a strong cross-association (O···H···N). Solid-liquid equilibrium of the systems measured in this work was determined from time-temperature warming curves. In both measured ternary systems with a small addition of the ionic liquid 1-butyl-3-methylimidazolium chloride (i.e. the systems acetic acid (1)-formamide (2)-1-butyl-3-methylimidazolium chloride (3) and propionic acid (1)-formamide (2)-1-butyl-3-methylimidazolium chloride (3)) the above mentioned stable solid compounds are formed and the corresponding melting temperature of these compounds decreased. Dissociation parameters were modelled thermodynamically for solid adducts.

Sign in / Sign up

Export Citation Format

Share Document