The Relationship Between Helical Twist Sense, Absolute Configuration and Molecular Structure for Non-Sterol Cholesteric Liquid Crystals

1976 ◽  
Vol 34 (9) ◽  
pp. 211-217 ◽  
Author(s):  
G. W. Gray ◽  
D. G. McDonnell
Keyword(s):  
Molecular Structure ◽  
Liquid Crystals ◽  
Absolute Configuration ◽  
Cholesteric Liquid Crystals ◽  
Helical Twist ◽  
The Relationship

Notizen: Bestimmung des Helixdrehsinnes cholesterischer Phasen mit der Grandjean-Cano-Methode / Determination of the Helical Sense of Cholesteric Liquid Crystals Using the Grandjean-Cano Method

1977 ◽  
Vol 32 (8) ◽  
pp. 899-902 ◽  
Author(s):  
G. Heppke ◽  
F. Oestreicher
Keyword(s):  
Molecular Structure ◽  
Liquid Crystals ◽  
Nematic Phase ◽  
Ring System ◽  
Cholesteric Liquid Crystals ◽  
Cholesteric Phase ◽  
Chiral Compounds ◽  
Helix Pitch

Abstract A simple way of determining the helix screw sense of a cholesteric phase using the Grandjean-Cano method is described. The helix pitch as well as its sense is investigated for ten cholesteric phases, induced by mesogenic chiral com­pounds in the nematic isomere mixture of 4-methoxy-4′-n-butylazoxybenzene (Nematic Phase 4, Merck). For the chiral compounds with nematic-like molecular structure it is found that the screw sense alternates with the number of bonds between the chiral centre and the ring system.

The Effect of Donor Molecular Structure on Power Conversion Efficiency of Small-Molecule-Based Organic Solar Cells

2019 ◽  
Vol 16 (3) ◽  
pp. 236-243 ◽  
Author(s):  
Hui Zhang ◽  
Yibing Ma ◽  
Youyi Sun ◽  
Jialei Liu ◽  
Yaqing Liu ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Solar Cells ◽  
Power Conversion Efficiency ◽  
Conversion Efficiency ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
Molecular Design ◽  
Power Conversion ◽  
The Relationship

In this review, small-molecule donors for application in organic solar cells reported in the last three years are highlighted. Especially, the effect of donor molecular structure on power conversion efficiency of organic solar cells is reported in detail. Furthermore, the mechanism is proposed and discussed for explaining the relationship between structure and power conversion efficiency. These results and discussions draw some rules for rational donor molecular design, which is very important for further improving the power conversion efficiency of organic solar cells based on the small-molecule donor.

scholarly journals Synthesis and Characterization of Novel Bio-Chiral Dopants Obtained from Bio-Betulin Produced by a Fermentation Process

Crystals ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 785
Author(s):  
Veridiana G. Guimarães ◽  
Anastasiia Svanidze ◽  
Tianyi Guo ◽  
Pawan Nepal ◽  
Robert J. Twieg ◽  
...  
Keyword(s):  
Liquid Crystals ◽  
Natural Product ◽  
Fermentation Process ◽  
Synthesis And Characterization ◽  
Cholesteric Liquid Crystals ◽  
And Performance ◽  
Chiral Dopants

Cholesteric liquid crystals are frequently produced by the addition of chiral dopants to achiral nematic hosts. We report here the synthesis and performance of chiral dopants obtained from bio-betulin produced by a fermentation process. An important aspect of this work is to point out that the fermentation process used to obtain the starting materials is much easier and cheaper when carried out in large volumes than isolating it from the natural product. The performance of the dopants obtained from bio-betulin is indistinguishable from those obtained from commercially available synthetic betulin.

scholarly journals Augmented Lagrangian preconditioners for the Oseen–Frank model of nematic and cholesteric liquid crystals

2021 ◽  
Author(s):  
Jingmin Xia ◽  
Patrick E. Farrell ◽  
Florian Wechsung
Keyword(s):  
Liquid Crystals ◽  
Augmented Lagrangian ◽  
Augmented Lagrangian Method ◽  
Mass Matrix ◽  
Unit Length ◽  
Mesh Size ◽  
Schur Complement ◽  
Cholesteric Liquid Crystals ◽  
Multigrid Algorithm ◽  
The Cost

AbstractWe propose a robust and efficient augmented Lagrangian-type preconditioner for solving linearizations of the Oseen–Frank model arising in nematic and cholesteric liquid crystals. By applying the augmented Lagrangian method, the Schur complement of the director block can be better approximated by the weighted mass matrix of the Lagrange multiplier, at the cost of making the augmented director block harder to solve. In order to solve the augmented director block, we develop a robust multigrid algorithm which includes an additive Schwarz relaxation that captures a pointwise version of the kernel of the semi-definite term. Furthermore, we prove that the augmented Lagrangian term improves the discrete enforcement of the unit-length constraint. Numerical experiments verify the efficiency of the algorithm and its robustness with respect to problem-related parameters (Frank constants and cholesteric pitch) and the mesh size.

scholarly journals Pitch tuning induced by optical torque in heliconical cholesteric liquid crystals

2019 ◽  
Vol 1 (3) ◽  
Author(s):  
G. Nava ◽  
F. Ciciulla ◽  
O. S. Iadlovska ◽  
O. D. Lavrentovich ◽  
F. Simoni ◽  
...  
Keyword(s):  
Liquid Crystals ◽  
Cholesteric Liquid Crystals ◽  
Optical Torque
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