Stabilization of a New Type of Water Octamer in the Crystalline Hydrate of an Inorganic‐organic Hybrid Material: Synthesis and Characterization of [{Cu(phen)(H2O)2}2(Mo8O26)] · 8H2O

2008 ◽  
Vol 38 (1) ◽  
pp. 12-17 ◽  
Author(s):  
Vaddypally Shivaiah ◽  
Tanmay Chatterjee ◽  
Samar K. Das
Keyword(s):  
Hybrid Material ◽  
Crystalline Hydrate ◽  
Synthesis And Characterization ◽  
Material Synthesis ◽  
Organic Hybrid ◽  
New Type ◽  
Organic Hybrid Material

A polyoxometalate-based inorganic–organic hybrid material: synthesis, characterization structure and photocatalytic study

2015 ◽  
Vol 70 (7) ◽  
pp. 461-466 ◽  
Author(s):  
Jingzhi Tian ◽  
Tao Jing ◽  
Yongjie Zheng
Keyword(s):  
Hybrid Material ◽  
Rhodamine B ◽  
X Ray Diffraction ◽  
Material Synthesis ◽  
Hybrid Compound ◽  
X Ray ◽  
Organic Hybrid ◽  
Rhodamine B Dye ◽  
Supramolecular Chains ◽  
Organic Hybrid Material

AbstractA new polyoxometalate (POM)-based inorganic–organic hybrid compound, [Ag2(bib)3][H2SiW12O40] (1), has been hydrothermally synthesized and characterized by routine methods. Single-crystal X-ray diffraction analysis reveals that inorganic supramolecular chains constructed of POM and [Ag2(bib)3] subunits are fused together via the Ag cations forming a 3D supramolecular structure. The structure possesses the moganite-type topology. The photocatalytic properties have been investigated through the oxidative decomposition of Rhodamine-B dye.

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