Implementation of a generalized least-squares method for determining calibration curves from data with general uncertainty structures

Metrologia ◽  
2006 ◽  
Vol 43 (4) ◽  
pp. S291-S298 ◽  
Author(s):  
M J T Milton ◽  
P M Harris ◽  
I M Smith ◽  
A S Brown ◽  
B A Goody
1982 ◽  
Vol 60 (15) ◽  
pp. 1978-1981 ◽  
Author(s):  
John W. Lorimer

A generalized least-squares method is described for finding the point of intersection of a family of straight lines, each of which is defined by two experimental points. It is shown that the method of the least-squares triangle (Can. J. Chem. 59, 3076 (1981)) is a good first approximation to the general method. An example demonstrates the method of iteration of both parameters and observations for a problem involving evaluation of solid phase compositions from solubility measurements.


Author(s):  
Jean-Pierre Florens ◽  
Velayoudom Marimoutou ◽  
Anne Peguin-Feissolle ◽  
Josef Perktold ◽  
Marine Carrasco

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