Crystal field of Dy implanted in Au single crystals, obtained by Mossbauer spectroscopy

1981 ◽  
Vol 11 (3) ◽  
pp. 547-556 ◽  
Author(s):  
P J Kikkert ◽  
L Niesen
Texture ◽  
1974 ◽  
Vol 1 (4) ◽  
pp. 259-263 ◽  
Author(s):  
E. Kreber ◽  
U. Gonser

In Mössbauer spectroscopy it is desirable to work with single crystals or with polycrystalline material of random orientation. The actual, most occuring, case of preferred orientation (texture) and its influence on the relative line intensities of hyperfine split Mössbauer spectra is analysed. Texture information which can be obtained from such an analysis is demonstrated with variously prepared barium ferrite (Ba Fe12 O19) samples.


1983 ◽  
Vol 44 (4) ◽  
pp. 307-309 ◽  
Author(s):  
D. Niarchos ◽  
P.J. Viccaro ◽  
G.K. Shenoy ◽  
B.D. Dunlap ◽  
J.K. Yakinthos

2013 ◽  
Vol 4 ◽  
pp. 807-814 ◽  
Author(s):  
Valeriu Mereacre ◽  
Frederik Klöwer ◽  
Yanhua Lan ◽  
Rodolphe Clérac ◽  
Juliusz A Wolny ◽  
...  

By using Mössbauer spectroscopy in combination with susceptibility measurements it was possible to identify the supertransferred hyperfine field through the oxygen bridges between DyIII and FeIII in a {Fe4Dy2} coordination cluster. The presence of the dysprosium ions provides enough magnetic anisotropy to “block” the hyperfine field that is experienced by the iron nuclei. This has resulted in magnetic spectra with internal hyperfine fields of the iron nuclei of about 23 T. The set of data permitted us to conclude that the direction of the anisotropy in lanthanide nanosize molecular clusters is associated with the single ion and crystal field contributions and 57Fe Mössbauer spectroscopy may be informative with regard to the the anisotropy not only of the studied isotope, but also of elements interacting with this isotope.


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