Structural transformations and physical properties of (1  −  x) Na0.5Bi0.5TiO3  −  x BaTiO3 solid solutions near a morphotropic phase boundary

2018 ◽  
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Tapabrata Dam ◽  
Hitesh Borkar ◽  
Dhiren K Pradhan ◽  
K K Mishra ◽  
...  
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Andrei N. Salak ◽  
Vladimir V. Shvartsman ◽  
João Pedro Cardoso ◽  
Anatoli V. Pushkarev ◽  
Yury V. Radyush ◽  
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2001 ◽  
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Hidehiro Ohwa ◽  
Motoyuki Kume ◽  
Yasuharu Hosono ◽  
Yohachi Yamashita ◽  
...  

2014 ◽  
Vol 2014 ◽  
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Nguyen Dinh Tung Luan ◽  
Le Dai Vuong ◽  
Truong Van Chuong ◽  
Nguyen Truong Tho

The 0.9Pb(ZrxTi1−x)O3-0.07Pb(Mn1/3Nb2/3)O3-0.03Pb(Sb1/2Nb1/2)O3(PZT-PMnN-PSN) ceramics were prepared by columbite method. The phase structure of the ceramic samples was analyzed. Results show that the pure perovskite phase is in all ceramics specimens. The effect of the Zr/Ti ratio on the region of morphotropic phase boundary for PZT-PMnN-PSN ceramics was studied. Experimental results show that the phase structure of ceramics changes from tetragonal to rhombohedral with the increase of the content of Zr/Ti ratio in the system. The composition of PZT-PMnN-PSN ceramics near the morphotropic phase boundary obtained is the ratio of Zr/Ti: 49/51. At this ratio, the ceramic has the optimal electromechanical properties: thekp=0.61, theεmax=29520, thed31=-236 pC/N, theQm=2400, high remanent polarization (Pr=49.2 μC·cm−2), and low coercive fieldEc=10.28 kV·cm−1.


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