scholarly journals Quasipotentials in the nonequilibrium stationary states or a method to get explicit solutions of Hamilton–Jacobi equations

2021 ◽  
Vol 2021 (11) ◽  
pp. 113206
Author(s):  
P L Garrido

Abstract We assume that a system at a mesoscopic scale is described by a field ϕ(x, t) that evolves by a Langevin equation with a white noise whose intensity is controlled by a parameter 1 / Ω . The system stationary state distribution in the small noise limit (Ω → ∞) is of the form P st [ϕ] ≃ exp(−ΩV 0[ϕ]), where V 0[ϕ] is called the quasipotential. V 0 is the unknown of a Hamilton–Jacobi equation. Therefore, V 0 can be written as an action computed along a path that is the solution from Hamilton’s equation that typically cannot be solved explicitly. This paper presents a theoretical scheme that builds a suitable canonical transformation that permits us to do such integration by deforming the original path into a straight line and including some weights along with it. We get the functional form of such weights through conditions on the existence and structure of the canonical transformation. We apply the scheme to get the quasipotential algebraically for several one-dimensional nonequilibrium models as the diffusive and reaction–diffusion systems.

2021 ◽  
Vol 126 (10) ◽  
Author(s):  
Fridtjof Brauns ◽  
Henrik Weyer ◽  
Jacob Halatek ◽  
Junghoon Yoon ◽  
Erwin Frey

2021 ◽  
Vol 7 (16) ◽  
pp. eabe3801
Author(s):  
Amanda J. Ackroyd ◽  
Gábor Holló ◽  
Haridas Mundoor ◽  
Honghu Zhang ◽  
Oleg Gang ◽  
...  

Chemical organization in reaction-diffusion systems offers a strategy for the generation of materials with ordered morphologies and structural hierarchy. Periodic structures are formed by either molecules or nanoparticles. On the premise of new directing factors and materials, an emerging frontier is the design of systems in which the precipitation partners are nanoparticles and molecules. We show that solvent evaporation from a suspension of cellulose nanocrystals (CNCs) and l-(+)-tartaric acid [l-(+)-TA] causes phase separation and precipitation, which, being coupled with a reaction/diffusion, results in rhythmic alternation of CNC-rich and l-(+)-TA–rich rings. The CNC-rich regions have a cholesteric structure, while the l-(+)-TA–rich bands are formed by radially aligned elongated bundles. The moving edge of the pattern propagates with a finite constant velocity, which enables control of periodicity by varying film preparation conditions. This work expands knowledge about self-organizing reaction-diffusion systems and offers a strategy for the design of self-organizing materials.


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