scholarly journals Comparison of differential and integral methods for coal oxidation kinetic analysis

2018 ◽  
Vol 1128 ◽  
pp. 012076
Author(s):  
K V Slyusarskiy ◽  
V E Gubin ◽  
D V Gvozdyakov ◽  
A A Tolokolnikov
2021 ◽  
Vol 1137 (1) ◽  
pp. 012011
Author(s):  
Swe Zin Win ◽  
Preechar Karin ◽  
Watanyoo Phairote ◽  
Nuwong Chollacoop ◽  
Peerawat Saisirirat ◽  
...  

2019 ◽  
Vol 33 (7) ◽  
pp. 6809-6816 ◽  
Author(s):  
Jianbing Gao ◽  
Haibo Chen ◽  
Guohong Tian ◽  
Chaochen Ma ◽  
Fei Zhu

2013 ◽  
Vol 437 (1-3) ◽  
pp. 310-316 ◽  
Author(s):  
M. Marchand ◽  
O. Fiquet ◽  
M. Brothier

2015 ◽  
Vol 1096 ◽  
pp. 243-247
Author(s):  
Lan Shu Xu ◽  
Yi Cheng ◽  
Yu Yu Li ◽  
Rui Li

Errors was generate when use integral methods to calculate pyrolysis kinetic. It was analyzed by considered the effects of methods and reaction orders. A α-T curve was established for the error discussion depending on basic kenotic theory. For analysis methods, both single curve and multiple curve methods can obtain reliable activation energy values (≤3%), but the error of frequency factor was significant (up to 40%). Frequency factor is sensitive to intercept changing and is also to reaction order. Magnitude error could show if reaction order deviates to true value.


1965 ◽  
Vol 13 (01) ◽  
pp. 155-175 ◽  
Author(s):  
H. C Hemker ◽  
P.W Hemker ◽  
E. A Loeliger

SummaryApplication of the methods of enzyme-kinetic analysis to the results of clotting tests is feasible and can yield useful results. However, the standard methods of enzyme kinetics are not applicable without modifications imposed by the peculiarities of the blood-clotting enzyme system. The influence of the following complicating circumstances is calculated :1. Substrate is not present in excess.2. Only relative measures exist for concentrations of substrate or enzymes.3. Enzymes and substrates are often added together.4. Reagents are not pure.5. Clotting-time is our only measure for clotting-velocity.Formulas are deduced, which makes it possible to recognize the effect of these complications.


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