Electrochemical Reduction of Carbon Dioxide on an Indium Wire in a KOH/Methanol-Based Electrolyte at Ambient Temperature and Pressure

1999 ◽  
Vol 16 (2) ◽  
pp. 131-137 ◽  
Author(s):  
SATOSHI KANECO ◽  
RYOSUKE IWAO ◽  
KENJI IIBA ◽  
SYN-ICHI ITOH ◽  
KIYOHISA OHTA ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Ambient Temperature ◽  
Electrochemical Reduction ◽  
Temperature And Pressure

Electrochemical conversion of carbon dioxide to formic acid on Pb in KOH/methanol electrolyte at ambient temperature and pressure

Energy ◽  
1998 ◽  
Vol 23 (12) ◽  
pp. 1107-1112 ◽  
Author(s):  
Satoshi Kaneco ◽  
Ryosuke Iwao ◽  
Kenji Iiba ◽  
Kiyohisa Ohta ◽  
Takayuki Mizuno
Keyword(s):  
Carbon Dioxide ◽  
Formic Acid ◽  
Ambient Temperature ◽  
Electrochemical Conversion ◽  
Temperature And Pressure

scholarly journals Phosphine-catalyzed fixation of CO2 with γ-hydroxyl alkynone under ambient temperature and pressure: kinetic resolution and further conversion

2019 ◽  
Vol 6 (14) ◽  
pp. 2420-2429 ◽  
Author(s):  
Yao-Liang Sun ◽  
Yin Wei ◽  
Min Shi
Keyword(s):  
Carbon Dioxide ◽  
Ambient Temperature ◽  
Kinetic Resolution ◽  
Carbon Dioxide Fixation ◽  
Temperature And Pressure ◽  
Propargyl Alcohols

Phosphine-catalyzed fixation of CO2 with γ-hydroxyl alkynone under ambient temperature and pressure was achieved and the first example of chiral phosphine catalyzed kinetic resolution of propargyl alcohols via carbon dioxide fixation was demonstrated.

Communication—Electrochemical Reduction of Nitrogen to Ammonia in 2-Propanol under Ambient Temperature and Pressure

2016 ◽  
Vol 163 (7) ◽  
pp. F610-F612 ◽  
Author(s):  
Kwiyong Kim ◽  
Nara Lee ◽  
Chung-Yul Yoo ◽  
Jong-Nam Kim ◽  
Hyung Chul Yoon ◽  
...  
Keyword(s):  
Ambient Temperature ◽  
Electrochemical Reduction ◽  
Temperature And Pressure

Activation of (salen)CoI complex by phosphorane for carbon dioxide transformation at ambient temperature and pressure

2017 ◽  
Vol 19 (16) ◽  
pp. 3908-3915 ◽  
Author(s):  
Feng Zhou ◽  
Shi-Liang Xie ◽  
Xiao-Tong Gao ◽  
Rong Zhang ◽  
Cui-Hong Wang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Ambient Temperature ◽  
Bifunctional Catalyst ◽  
Carbon Dioxide Pressure ◽  
Temperature And Pressure

The activation of a (salen)CoI complex by phosphorane in situ formed a bifunctional catalyst for the reaction of carbon dioxide with terminal epoxides or aziridines at ambient temperature and 1 bar carbon dioxide pressure.

Highly Selective Electrochemical Reduction of Dinitrogen to Ammonia at Ambient Temperature and Pressure over Iron Oxide Catalysts

2018 ◽  
Vol 24 (69) ◽  
pp. 18494-18501 ◽  
Author(s):  
Xiaoyang Cui ◽  
Cheng Tang ◽  
Xiao‐Meng Liu ◽  
Chen Wang ◽  
Wenjun Ma ◽  
...  
Keyword(s):  
Iron Oxide ◽  
Ambient Temperature ◽  
Electrochemical Reduction ◽  
Oxide Catalysts ◽  
Temperature And Pressure

Photochemical and Electrochemical Reduction of Carbon Dioxide Catalyzed by a Polyoxometalate-Organic Photosensitizer Complex

2018 ◽  
Author(s):  
Chandan Dey ◽  
Ronny Neumann
Keyword(s):  
Carbon Dioxide ◽  
Cyclic Voltammetry ◽  
Formic Acid ◽  
Electrochemical Reduction ◽  
Mass Spectroscopy ◽  
Photochemical Reactions ◽  
Reducing Agent ◽  
Covalent Attachment ◽  
Hybrid Complex ◽  
Open Face

<p>A manganese substituted Anderson type polyoxometalate, [MnMo<sub>6</sub>O<sub>24</sub>]<sup>9-</sup>, tethered with an anthracene photosensitizer was prepared and used as catalyst for CO<sub>2</sub> reduction. The polyoxometalate-photosensitizer hybrid complex, obtained by covalent attachment of the sensitizer to only one face of the planar polyoxometalate, was characterized by NMR, IR and mass spectroscopy. Cyclic voltammetry measurements show a catalytic response for the reduction of carbon dioxide, thereby suggesting catalysis at the manganese site on the open face of the polyoxometalate. Controlled potentiometric electrolysis showed the reduction of CO<sub>2</sub> to CO with a TOF of ~15 sec<sup>-1</sup>. Further photochemical reactions showed that the polyoxometalate-anthracene hybrid complex was active for the reduction of CO<sub>2</sub> to yield formic acid and/or CO in varying amounts dependent on the reducing agent used. Control experiments showed that the attachment of the photosensitizer to [MnMo<sub>6</sub>O<sub>24</sub>]<sup>9-</sup> is necessary for photocatalysis.</p><div><br></div>

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