Redox Thermodynamics for Oxygen Species (O3, O2, HOO·, O2-, HOOH, HOO-, O, O-, and HO-); Effects of Media and pH

Oxygen Chemistry ◽

10.1093/oso/9780195057980.003.0006 ◽

1992 ◽

Author(s):

Donald T. Sawyer ◽

R. J. P. Williams

Keyword(s):

Electron Transfer ◽

Photosystem Ii ◽

Oxygen Atom ◽

Ground State ◽

Energy Transduction ◽

Oxygen Species ◽

Oxygen Atom Transfer ◽

Green Plants ◽

Redox Thermodynamics ◽

Effects Of Media

Biological systems activate ground-state dioxygen (3O2) for controlled energy transduction and chemical syntheses via electron-transfer and hydrogen-atomtransfer reduction to O2-, HOO·, and HOOH. These reduction products are further activated with metalloproteins to accomplish oxygen atom-transfer chemistry. Conversely, green plants via photosystem II facilitate the oxidation of chemistry.

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Activation of Nitroarenes in the Homogenous Catalytic Carbonylation of Nitroaromatics via an Oxygen-Atom-Transfer Mechanism Induced by Inner-Sphere Electron Transfer†

Journal of the American Chemical Society ◽

10.1021/ja971899w ◽

1997 ◽

Vol 119 (45) ◽

pp. 11049-11060 ◽

Cited By ~ 41

Author(s):

Steven J. Skoog ◽

Wayne L. Gladfelter

Keyword(s):

Electron Transfer ◽

Oxygen Atom ◽

Transfer Mechanism ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Inner Sphere ◽

Catalytic Carbonylation

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Photochemical oxygen-atom transfer reaction by heterocycle N-oxides involving a single-electron transfer process: oxidative demethylation of N,N-dimethylaniline

Journal of the American Chemical Society ◽

10.1021/ja00279a063 ◽

1986 ◽

Vol 108 (19) ◽

pp. 6039-6041 ◽

Cited By ~ 27

Author(s):

Magoichi. Sako ◽

Kaoru. Shimada ◽

Kosaku. Hirota ◽

Yoshifumi. Maki

Keyword(s):

Electron Transfer ◽

Oxygen Atom ◽

Transfer Process ◽

Transfer Reaction ◽

Single Electron ◽

Atom Transfer ◽

Single Electron Transfer ◽

Oxygen Atom Transfer ◽

Electron Transfer Process ◽

Oxidative Demethylation

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Stereochemical Consequences of Oxygen Atom Transfer and Electron Transfer in Imido/Oxido Molybdenum(IV, V, VI) Complexes with Two Unsymmetric Bidentate Ligands

Inorganic Chemistry ◽

10.1021/ic202588u ◽

2012 ◽

Vol 51 (7) ◽

pp. 4180-4192 ◽

Cited By ~ 27

Author(s):

Kristina Hüttinger ◽

Christoph Förster ◽

Timo Bund ◽

Dariush Hinderberger ◽

Katja Heinze

Keyword(s):

Electron Transfer ◽

Oxygen Atom ◽

Atom Transfer ◽

Bidentate Ligands ◽

Oxygen Atom Transfer

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ChemInform Abstract: SOLVENT AND STRUCTURAL EFFECTS ON PICOSECOND ELECTRON TRANSFER REACTIONS IN DIPORPHYRIN MODELS OF THE PHOTOSYSTEM II REACTION CENTER OF GREEN PLANTS

Chemischer Informationsdienst ◽

10.1002/chin.198251147 ◽

1982 ◽

Vol 13 (51) ◽

Author(s):

I. FUJITA ◽

J. FAJER ◽

C.-K. CHANG ◽

C.-B. WANG ◽

M. A. BERGKAMP ◽

...

Keyword(s):

Electron Transfer ◽

Photosystem Ii ◽

Reaction Center ◽

Transfer Reactions ◽

Structural Effects ◽

Electron Transfer Reactions ◽

Green Plants

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Metal- and additive-free oxygen-atom transfer reaction: an efficient and chemoselective oxidation of sulfides to sulfoxides with cyclic diacyl peroxides

Organic & Biomolecular Chemistry ◽

10.1039/c7ob00021a ◽

2017 ◽

Vol 15 (12) ◽

pp. 2647-2654 ◽

Cited By ~ 18

Author(s):

Shaoyan Gan ◽

Junjie Yin ◽

Yuan Yao ◽

Yang Liu ◽

Denghu Chang ◽

...

Keyword(s):

Electron Transfer ◽

Oxygen Atom ◽

Transfer Reaction ◽

Transfer Mechanism ◽

Atom Transfer ◽

Oxygen Atom Transfer ◽

Free Oxygen ◽

Electron Transfer Mechanism ◽

Oxidation Of Sulfides

Metal- and additive-free sulfoxidation was developed using cyclic diacyl peroxides as oxygen sources and a single two-electron transfer mechanism was suggested.

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