Activation of Nitroarenes in the Homogenous Catalytic Carbonylation of Nitroaromatics via an Oxygen-Atom-Transfer Mechanism Induced by Inner-Sphere Electron Transfer†

1997 ◽  
Vol 119 (45) ◽  
pp. 11049-11060 ◽  
Author(s):  
Steven J. Skoog ◽  
Wayne L. Gladfelter
Keyword(s):  
Electron Transfer ◽  
Oxygen Atom ◽  
Transfer Mechanism ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Inner Sphere ◽  
Catalytic Carbonylation

Metal- and additive-free oxygen-atom transfer reaction: an efficient and chemoselective oxidation of sulfides to sulfoxides with cyclic diacyl peroxides

2017 ◽  
Vol 15 (12) ◽  
pp. 2647-2654 ◽  
Author(s):  
Shaoyan Gan ◽  
Junjie Yin ◽  
Yuan Yao ◽  
Yang Liu ◽  
Denghu Chang ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Mechanism ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Free Oxygen ◽  
Electron Transfer Mechanism ◽  
Oxidation Of Sulfides

Metal- and additive-free sulfoxidation was developed using cyclic diacyl peroxides as oxygen sources and a single two-electron transfer mechanism was suggested.

Stereochemical Consequences of Oxygen Atom Transfer and Electron Transfer in Imido/Oxido Molybdenum(IV, V, VI) Complexes with Two Unsymmetric Bidentate Ligands

2012 ◽  
Vol 51 (7) ◽  
pp. 4180-4192 ◽  
Author(s):  
Kristina Hüttinger ◽  
Christoph Förster ◽  
Timo Bund ◽  
Dariush Hinderberger ◽  
Katja Heinze
Keyword(s):  
Electron Transfer ◽  
Oxygen Atom ◽  
Atom Transfer ◽  
Bidentate Ligands ◽  
Oxygen Atom Transfer

Mechanistic insight into oxygen atom transfer reactions by mononuclear manganese(iv)–oxo adducts

2021 ◽  
Vol 50 (10) ◽  
pp. 3577-3585
Author(s):  
Priya Singh ◽  
Eleanor Stewart-Jones ◽  
Melissa C. Denler ◽  
Timothy A. Jackson
Keyword(s):  
Oxygen Atom ◽  
Kinetic Studies ◽  
Transfer Mechanism ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Mechanistic Insight ◽  
P Rate ◽  
Oxygen Atom Transfer Reactions ◽  
Insight Into

Rate enhancements in sulfoxidation reactions are often associated with a change in mechanism. Kinetic studies of sulfoxidation reactions by a series of MnIV–oxo complexes reveal large rate changes while retaining an oxygen-atom transfer mechanism.

Oxygen Atom Transfer Mechanism for Vanadium‐Oxo Porphyrin Complexes Mediated the Aerobic Olefin Epoxidation

2021 ◽  
Author(s):  
Xiao‐Hui Liu ◽  
Jia‐Ying Huang ◽  
Lei‐Ming Tao ◽  
Hai‐Yang Yu ◽  
Xian‐Tai Zhou ◽  
...  
Keyword(s):  
Oxygen Atom ◽  
Transfer Mechanism ◽  
Atom Transfer ◽  
Olefin Epoxidation ◽  
Oxygen Atom Transfer

Proton-Promoted Oxygen Atom Transfer vs Proton-Coupled Electron Transfer of a Non-Heme Iron(IV)-Oxo Complex

2012 ◽  
Vol 134 (8) ◽  
pp. 3903-3911 ◽  
Author(s):  
Jiyun Park ◽  
Yuma Morimoto ◽  
Yong-Min Lee ◽  
Wonwoo Nam ◽  
Shunichi Fukuzumi
Keyword(s):  
Electron Transfer ◽  
Oxygen Atom ◽  
Heme Iron ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Proton Coupled Electron Transfer ◽  
Non Heme Iron
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