scholarly journals Absolute NMR shielding scales in methyl halides obtained from experimental and calculated nuclear spin-rotation constants

2021 ◽  
Vol 104 (1) ◽  
Author(s):  
Daniel F. E. Bajac ◽  
I. Agustín Aucar ◽  
Gustavo A. Aucar
2003 ◽  
Vol 22 (2) ◽  
pp. 199-207 ◽  
Author(s):  
P. Cacciani ◽  
J. Cosléou ◽  
F. Herlemont ◽  
M. Khelkhal ◽  
J. Legrand

1998 ◽  
Vol 57 (6) ◽  
pp. 4296-4300 ◽  
Author(s):  
E. Ilisca ◽  
K. Bahloul

1995 ◽  
Vol 84 (3) ◽  
pp. 627-632 ◽  
Author(s):  
Yu.A. Serebrennikov ◽  
U.E. Steiner

2021 ◽  
Vol 155 (13) ◽  
pp. 134307
Author(s):  
Ignacio Agustín Aucar ◽  
Anastasia Borschevsky
Keyword(s):  

1991 ◽  
Vol 69 (7) ◽  
pp. 1054-1056 ◽  
Author(s):  
Glenn H. Penner

Selenium-77 and phosphorus-31 spin-lattice relaxation times are reported for tri-tert-butylphosphine selenide in chloroform-d, at 303 K and at several different magnetic field strengths. At moderate fields the 31P–1H dipole–dipole, spin-rotation, and chemical shift anisotropy mechanisms contribute significantly towards the 31P T1. At high fields chemical shift anisotropy dominates. The selenium-77 nuclear spin relaxes almost exclusively by spin rotation at low to moderate fields and the chemical shift anisotropy contribution only becomes significant at very high fields. This is due to an unusually small 77Se CSA. The contribution due to 31P–77Se dipole–dipole interactions is small but significant. Key words: 77Se NMR, NMR relaxation, phosphine selenide.


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