Nonimpact theory of resonance Raman line shapes in strong radiation fields

1982 ◽  
Vol 26 (1) ◽  
pp. 341-355 ◽  
Author(s):  
Shaul Mukamel ◽  
Danielle Grimbert ◽  
Yitzhak Rabin
2004 ◽  
Vol 76 (1) ◽  
pp. 147-155 ◽  
Author(s):  
M. Musso ◽  
F. Matthai ◽  
D. Keutel ◽  
K.-L. Oehme

Isotropic Raman line shapes of simple molecular fluids exhibit critical line broadening near their respective liquid-gas critical points. In order to observe this phenomenon, it is essential that the band position of a given vibrational mode is density-dependent, and that vibrational depopulation processes negligibly contribute to line broadening. Special attention was given to the fact that the isotropic (i.e., nonrotationally broadened) line shape of liquid N2 is affected by resonant intermolecular vibrational interactions between identical oscillators. By means of the well-chosen isotopic mixture (14N2).975 - (14N15N).025, the temperature and density dependences of shift, width, and asymmetry of the resonantly coupled 14N2 and, depending on the S/N ratio available, of the resonantly uncoupled 14N15N were determined, with up to milli-Kelvin resolution, in the coexisting liquid and gas phases and along the critical isochore, using a highest-resolution double monochromator and modern charge-coupled device detection techniques. Clear evidence was found that vibrational resonance couplings are present in all dense phases studied.


1998 ◽  
Vol 188 ◽  
pp. 413-414
Author(s):  
Y. Watanabe ◽  
J. Fukue

Accretion-disk corona (ADC) is required from observational as well as theoretical reasons. In almost all of traditional studies, however, a stationary corona has been assumed; i.e., the corona gas corotates with the underlying (Keplerian) accretion disk, and the radial motion is ignored. Recently, in the theory of accretion disks a radiative interaction between the gas and the external radiation field has attracted the attention of researchers. In particular the radiation drag between the gas and the external radiation field becomes important from the viewpoint of the angular-momentum removal. We thus examine the effect of radiation drag on the accretion-disk corona above/below the accretion disk (Watanabe, Fukue 1996a, b). We suppose that an accretion disk can be described by the standard disk, and that radiation fields are produced by the central luminous source and the accretion disk, itself. In general an accretion-disk corona under the influence of strong radiation fields dynamically infalls (advected) toward the center.


1971 ◽  
Vol 39 (2) ◽  
pp. 154-158
Author(s):  
I. Laulicht ◽  
V. Halpern

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