Summertime turbulent heat fluxes at East Antarctica over neighbouring rocky and ice shelf sites

During the ninth Indian Scientific Expedition to Antarctica, in the year 1990, a micro-meteorological tower was installed at Maitri (70° S, 12° E) on the rocky terrain and on an experimental basis, on the nearby ice-shelf at the location of Dakshin Gangotri (70° 7¢ S, 11° 7¢ E). The synoptic features strongly influencing over the sites are the southeasterly katabatic winds from the polar cap and/or northerly low level warm and humid winds from the sea. These flows are responsible for the formation of strong surface based inversion and strong convective conditions at the ice shelf and rocky terrain during the minimum and maximum insolation periods, respectively. This paper presents a study of surface layer structure over two contrasting surfaces on near-coastal Antarctica and deals with the significance of the energy exchange processes over the rocky Antarctic region and the parameterization of turbulent fluxes over surfaces having strong inversion/convection conditions. The paper makes use of turbulence structure functions which are different from the conventional one given by Panofsky and Dutton (1984).

Marked Changes in Biochar’s Ability to Directly Immobilize Cd in Soil: Implication for Biochar Remediation of Cd Contaminated Soil

To investigate the change in biochar’s ability to directly immobilize Cd in soil ，a successive wheat cultivation with experiment was conducted. Three biochar with different Cd adsorption mechanisms were added into soils and a mesh bag was used to separate the soil particles (> 1 μm) from biochar. The results showed that the ash contents and anionic contents (CO 3 2- and PO 4 3- ) of the biochar decreased with the cultivation time, while the oxygen-containing functional groups content and CEC of the biochar increased. Resultly, the Cd concentration on biochar decreased, highly decreased by 68.9% for WBC300, while unstable Cd species (acid soluble and reducible fraction of Cd) on biochar increased with successive cultivation, increasing from 3% to 17% for WBC300 in FS. Correspondingly, the ability of biochar to inhibit Cd accumulation in wheat decreased. The results of this study illustrated that the ability of biochar to directly immobilize Cd in soil is not permanent, it gradually decreases with aging in soil. The adsorption mechanism of Cd on biochar changed from precipitation to complexation and ion exchange processes could be the main reason.

Damming Weakens the Groundwater and Surface Water Exchange and Its Nitrate Removal in Semi-arid Prairie Rivers

Surface water (SW)-Groundwater (GW) exchange plays a vital role in a prairie aquatic system and the biogeochemical cycling in such a system. Considering the inadequate understanding of damming on SW-GW exchange, a damming prairie river in Southeast Eurasian steppe was chosen to investigate variations of the SW-GW exchange and its influences on the fate of nitrate (NO3-). Both hydraulic and hydrochemical methods were applied to precisely depict the daily and seasonal exchange processes. The upstream and downstream reaches of the dam were observed to be upwelling and downwelling conditions respectively within a hydrologic year. Results obtained from multiple tracer methods and hydraulic method indicate that damming contributed to transfer the stream from the upwelling to the downwelling condition and weaken the SW-GW exchange in the downstream. The patterns of SW-GW exchange modulated the NO3- uptake or production between the SW and the GW. NO3- was mainly removed in the SW-GW exchange zone (SW-GW EZ) of the upwelling segment, while produced in the downwelling segment. Both the removal and production of NO3- were enhanced during snowmelt period, which might be an active period for the SW-GW exchange and NO3- fate. This study underscores the negative effect of damming on the SW-GW exchange and accompanied NO3- removal in prairie river systems.

Comprehensive Studies of the Processes of the Molecular Transfer of the Momentum, Thermal Energy and Mass in the Nutrient Media of Biotechnological Industries

This article puts forward arguments in favor of the necessity of conducting complex measurements of molecular transport coefficients that quantitatively determine the coefficients of dynamic viscosity, thermal diffusivity and molecular diffusion. The rheological studies have been carried out on the viscometers of two types: those with a rolling ball (HÖPPLER® KF 3.2.), and those with a rotary one (Rheotest RN 4.1.). The thermophysical studies have been performed using the analyzer Hot Disk TPS 2500S. The measurements have been taken in the temperature range of 283 to 363 K. The concentration of dry substances has varied from 16.2 to 77.7% dry wt. An empirical equation for calculating the density of aqueous solutions of beet molasses has been obtained. The diagrams of the dependence of the dynamic viscosity on the shear rate in the range of 1 s−1 to 500 s−1 at different temperatures have been provided. The diagrams of the dependence of the coefficients of thermal conductivity and thermal diffusivity on the temperature and the concentration of dry substances have been presented, and empirical equations for their calculation have been obtained. The findings can be used for engineering calculations of hydrodynamic and heat-exchange processes in biotechnological equipment.

Heat transfer for the boiling crisis in porous systems

In this paper we analized and investigated the heat exchange crisis of boiling in porous structures, applicable in thermal power plants. Then we describe the heat exchange processes mechanism and determined the ideal sizes and thicknesses of porous structures. The designed porous structures can be implemented in gas turbine’s nozzles and combustion chambers. From an environmental point of view, the consumption coolant liquid is reduced by ten times in comparison the standard flow system. It’s effectively to develop mesh structures to allow the extension of the critical loads and manage the surface border.

Interfacial properties of chitosan lactate at the liquid/air interface

The interfacial properties (dynamic and equilibrium surface tension, viscosity and elasticity moduli) of chitosan lactate have been studied at the liquid/air interface by the oscillating drop shape method. Isotherms of dynamic surface tension of chitosan lactate are similar to dependences for other polyelectrolyte solutions, in particular for proteins. Chitosan is a weak cationic polyelectrolyte which can change its conformation from a linear rod to a chaotic and compacted coil. Therefore, the experimental dependence of the equilibrium surface tension on concentration of chitosan lactate was analyzed with the adsorption model proposed earlier for proteins. This model accounts the possibility of polyelectrolyte molecules existence in surface layer in n states with different molar surface varying from the maximum value at very low surface coverage by polyelectrolyte molecules to a minimum value at high surface coverage. Good agreement between the calculated and experimental values of surface tension was observed. The dependences of the elasticity and viscosity moduli of chitosan lactate solutions on the drop oscillations frequency are conditioned by the influence of exchange processes both between the surface layer and the bulk solution and in the surface layer itself. An increase of the solution concentration intensifies the exchange processes, and an increase of the oscillation frequency suppresses them. It is shown that the dependence of the surface viscoelasticity modulus of chitosan lactate is extreme in nature with a pronounced maximum. The reason for such behavior is the possibility of changing the molar surface area of the polyelectrolyte at the interface dependent on the amount of adsorption and its structural properties. Attempt of theoretical description of the viscoelasticity modulus within the framework of model accounting mono- or bilayer adsorption did not lead to a satisfactory result, possibly due to barrier adsorption mechanism of chitosan. But bilayer model provide qualitative description of extreme behavior of surface viscoelasticity on concentration. The values of the surface viscoelasticity modulus of chitosan lactate occupy an intermediate position in comparison with the data available in the literature for globular and flexible-chain proteins, that is consistent with their molecular structure. In addition, the work shows the applicability of the adsorption model, developed earlier for proteins in the framework of a nonideal two-dimensional solution theory, for describing the surface properties of other polyelectrolytes. This makes it possible to obtain qualitative and quantitative information about the processes occurring in the systems under study.