Theory of the metal-insulator transition in dicyanoquinonediimine salt mixed-valence organic conductors

1995 ◽  
Vol 51 (16) ◽  
pp. 10293-10300 ◽  
Author(s):  
T. Ogawa ◽  
Y. Suzumura
1997 ◽  
Vol 56 (12) ◽  
pp. R7053-R7056 ◽  
Author(s):  
L. Sheng ◽  
D. Y. Xing ◽  
D. N. Sheng ◽  
C. S. Ting

Crystals ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 775
Author(s):  
Hiroki Akutsu ◽  
Yuta Koyama ◽  
Scott S. Turner ◽  
Keigo Furuta ◽  
Yasuhiro Nakazawa

New bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF)-, bis(ethylenediseleno)tetrathiafulvalene (BEST)- and bis(ethylenedithio)tetraselenafulvalene (BETS)-based organic charge-transfer (CT) salts—α-(BEDT-TTF)3(HOC2H4SO3)2 (1), β-(BEST)3(HOC2H4SO3)2·H2O (2) and α-(BETS)2(HOC2H4SO3)·H2O (3)—have been prepared. Salts 1 and 2 show semiconducting behaviour. Salt 3, which is almost isostructural to α-(BETS)2I3, shows metallic behaviour down to 70 K and then shows a broader metal–insulator transition than that of α-(BETS)2I3. The reason for the difference in behaviour is estimated by the comparison of the Madelung energies of the full set of patterns of possible donor’s charge-ordered and anion’s disordered states.


2004 ◽  
Vol 114 ◽  
pp. 277-281 ◽  
Author(s):  
J. Wosnitza ◽  
J. Hagel ◽  
O. Stockert ◽  
C. Pfleiderer ◽  
J. A. Schlueter ◽  
...  

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