Effect of flow field and geometry on the dynamic contact angle

2007 ◽  
Vol 75 (5) ◽  
Author(s):  
A. V. Lukyanov ◽  
Y. D. Shikhmurzaev
1997 ◽  
Vol 334 ◽  
pp. 211-249 ◽  
Author(s):  
YULII D. SHIKHMURZAEV

A general mathematical model which describes the motion of an interface between immiscible viscous fluids along a smooth homogeneous solid surface is examined in the case of small capillary and Reynolds numbers. The model stems from a conclusion that the Young equation, σ1 cos θ = σ2 − σ3, which expresses the balance of tangential projection of the forces acting on the three-phase contact line in terms of the surface tensions σi and the contact angle θ, together with the well-established experimental fact that the dynamic contact angle deviates from the static one, imply that the surface tensions of contacting interfaces in the immediate vicinity of the contact line deviate from their equilibrium values when the contact line is moving. The same conclusion also follows from the experimentally observed kinematics of the flow, which indicates that liquid particles belonging to interfaces traverse the three-phase interaction zone (i.e. the ‘contact line’) in a finite time and become elements of another interface – hence their surface properties have to relax to new equilibrium values giving rise to the surface tension gradients in the neighbourhood of the moving contact line. The kinematic picture of the flow also suggests that the contact-line motion is only a particular case of a more general phenomenon – the process of interface formation or disappearance – and the corresponding mathematical model should be derived from first principles for this general process and then applied to wetting as well as to other relevant flows. In the present paper, the simplest theory which uses this approach is formulated and applied to the moving contact-line problem. The model describes the true kinematics of the flow so that it allows for the ‘splitting’ of the free surface at the contact line, the appearance of the surface tension gradients near the contact line and their influence upon the contact angle and the flow field. An analytical expression for the dependence of the dynamic contact angle on the contact-line speed and parameters characterizing properties of contacting media is derived and examined. The role of a ‘thin’ microscopic residual film formed by adsorbed molecules of the receding fluid is considered. The flow field in the vicinity of the contact line is analysed. The results are compared with experimental data obtained for different fluid/liquid/solid systems.


Author(s):  
O.N Goncharova ◽  
◽  
I.V. Marchuk ◽  
A.V. Zakurdaeva ◽  
◽  
...  

2013 ◽  
Vol 333-335 ◽  
pp. 2004-2009
Author(s):  
Lin Ling Jiang ◽  
Wei Mo ◽  
Xiao Jing Yang ◽  
Tian Li Xue ◽  
Shao Jian Ma

To better understand the sedimentation processes of bentonite, the sedimentation characteristic of bentonite suspension was studied by using the sedimentation analysis module of Dynamic Contact Angle Meter and Tensiometer. The results indicated that sedimentation characteristics of bentonite suspension were affected by the concentration and pH values of the suspension together with the dosage of dispersants. The natural sedimentation rates of bentonite suspension declined firstly with prolonging the sedimentation time and soon stabilized after about 50s. The sedimentation weight of particles hardly changed when the concentration ranged from 0.5% to 5.0%, while it increased significantly when ranged from 5.0% to 10.0%. The sedimentation weight and rate were relatively bigger at 4.4, 11.8 than that of 6.0, 7.9, and the maximum values appeared at pH11.8. Adding sodium pyrophosphate could improve the dispersibility of bentonite suspension.


Polymer ◽  
1996 ◽  
Vol 37 (16) ◽  
pp. 3659-3664 ◽  
Author(s):  
T. Kasemura ◽  
S. Takahashi ◽  
N. Nakane ◽  
T. Maegawa

Author(s):  
Dongin Yu ◽  
Chiwoong Choi ◽  
Moohwan Kim

At two-phase flow in microchannels, slug flow regime is different for wettability of surface. A slug in a hydrophilic microchannel has liquid film. However, a slug in a hydrophobic microchannel has no liquid film instead, the slug has triple-lines and makes higher pressure drop due to the motion of the triple-line. In previous researches, pressure drop of triple-line is depended of dynamic contact angle, channel diameter and fluid property. And, dynamic contact angle is depended of static contact angle, superficial velocity and fluid property. In order to understand the pressure drop of motion of triple-lines, pressure drop of slug with triple-lines in case of various diameters (0.546, 0.763, 1.018, 1.555, 2.075 mm), various fluids (D.I.water, D.I.water-1, 5, 10% ethanol mixture) and various superficial velocity (j = 0.01∼0.4 m/s) was measured. Dynamic contact angle was calculated from relation of the pressure drop of slug with triple-lines. Comparing with previous dynamic contact angle correlations, previous correlation underestimated dynamic contact angle in the region of this study. (10−4≤Ca≤10−3, 10−2≤We≤10−1, 68°≤θS≤110°)


Sign in / Sign up

Export Citation Format

Share Document