trans-Dimethanolbis(1,1,1-trifluoro-5,5-dimethylhexane-2,4-dionato)cobalt(II)

2007 ◽  
Vol 63 (11) ◽  
pp. m2639-m2639 ◽  
Author(s):  
Jordan O. Lerach ◽  
Matthias Zeller ◽  
Brian D. Leskiw
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Inversion Center ◽  
Intermolecular Hydrogen Bonds ◽  
Distorted Octahedral ◽  
Hydroxy Groups ◽  
Hydrogen Bonded

The Co atom of the title compound, [Co(C8H10F3O2)2(CH3OH)2], which is located on a crystallographic inversion center, exhibits a distorted octahedral geometry. The bidentate acetylacetonate-like ligands are in a trans arrangement. The plane through the acetylacetonate unit is tilted with respect to the CoO4 plane by 17.41 (7)°, which is in the same range as observed for similar Co(acac)2OR 2 derivatives. Via the methanol hydroxy groups, each molecule participates in two pairs of intermolecular hydrogen bonds that create a network of hydrogen-bonded chains along the direction of the a axis.

scholarly journals Bis(2,2′,2′′-nitrilotriacetamide-κ3O,N,O′)nickel(II) dinitrate tetrahydrate

2013 ◽  
Vol 69 (2) ◽  
pp. m89-m89 ◽  
Author(s):  
Xiao-Hui Deng ◽  
Qi-Jun Nie ◽  
Feng-Juan Zhu
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Three Dimensional ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Inversion Center ◽  
Lattice Water ◽  
Distorted Octahedral ◽  
Nitrate Anions

In the title compound, [Ni(C6H12N4O3)2](NO3)2·4H2O, the NiIIcation is located on an inversion center and isN,O,O′-chelated by two nitrilotris(acetamide) molecules in a distorted octahedral geometry. The complex cations, nitrate anions and lattice water molecules are connected by O—H...O and N—H...O hydrogen bonds, forming a three-dimensional supramolecular structure.

scholarly journals Bis(n-dodecylammonium) bis(chloranilato)diethanolcuprate(II)

2014 ◽  
Vol 70 (2) ◽  
pp. m63-m64 ◽  
Author(s):  
Akiko Himegi ◽  
Satoshi Kawata
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Two Dimensional ◽  
Inversion Center ◽  
Axis Direction ◽  
Compound C ◽  
Dimensional Network ◽  
Distorted Octahedral

In the title compound, (C12H25NH3)2[Cu(C6Cl2O4)2(C2H5OH)2], the CuIIatom lies on a crystallographic inversion center and is coordinated in a distorted octahedral geometry by four O atoms of two chloranilate ligands and two O atoms of two ethanol molecules which aretransto each other in the axial positions. In the crystal, the CuIImononuclear dianions are linked by O—H...O hydrogen bonds into a tape along thea-axis direction. The tapes are linked through N—H...O hydrogen bonds between the dianion and then-dodecylammonium cation, forming a two-dimensional network parallel to theabplane.

scholarly journals trans-Diaquabis[(E)-3-(dimethylamino)-1-(2-pyridyl)prop-2-en-1-one-κ2N1,O]cobalt(II) dinitrate dihydrate

2009 ◽  
Vol 65 (6) ◽  
pp. m633-m633 ◽  
Author(s):  
Jian-Hong Bi
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Crystal Packing ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Inversion Center ◽  
Distorted Octahedral

In the title compound, [Co(C10H12N2O)2(H2O)2](NO3)2·2H2O, the CoIIion, located on an inversion center, istrans-coordinated by twoN,O-bidentate chelating (E)-3-(dimethylamino)-1-(2-pyridyl)prop-2-en-1-one ligands and by two water molecules in a slightly distorted octahedral geometry. Intermolecular O—H...O hydrogen bonds link the cations, anions and water molecules into layers parallel to theacplane. The crystal packing also exhibits weak intermolecular C—H...O hydrogen bonds.

scholarly journals Poly[μ2-aqua-aqua[μ3-N-butyl-N-(2-hydroxyethyl)dithiocarbamato-κ3O,O′:S]sodium]

2016 ◽  
Vol 72 (2) ◽  
pp. 196-198 ◽  
Author(s):  
Muzzaffar A. Bhat ◽  
Shalini Jain ◽  
Sanjay K. Srivastava ◽  
Ray J. Butcher ◽  
Jan Wikaira
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Van Der Waals ◽  
Van Der Waals Forces ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Inversion Center ◽  
Distorted Octahedral ◽  
Polymeric Layer

In the title compound, [Na(C7H14NOS2)(H2O)2]n, the NaIcation is coordinated by five O atoms [Na—O = 2.3142 (11)–2.4677 (10) Å] from three aqua and twoN-butyl-N-(2-hydroxyethyl)dithiocarbamate (L) ligands and one S atom [Na—S = 3.0074 (6) Å] from a thirdLligand in a highly distorted octahedral geometry. Two aqua ligands related by an inversion center bridge two NaIcations, and eachLligand coordinates three NaIcations, leading to a layered arrangement aligned parallel to thebcplane. Intermolecular O—H...S hydrogen bonds are observed in the inner part of each polymeric layer; these are packed along theaaxis and held together by weak van der Waals forces.

Bis(2-methylimidazolium) bis(2-methylimidazole-κN)bis(salicylato-κ2 O,O′)manganese(III) bis(methanol-κO)bis(salicylato-κ2 O,O′)manganese(III) methanol disolvate

2006 ◽  
Vol 62 (4) ◽  
pp. m887-m888
Author(s):  
Lu-Tong Yuan ◽  
Zuo-Xiang Wang ◽  
An-Yu Zhou ◽  
Chun-Yi Liu ◽  
Xiao-Yong Chou
Keyword(s):  
Title Compound ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Inversion Center ◽  
Compound C ◽  
Distorted Octahedral ◽  
Complex Anions ◽  
Hydrogen Bonded

In the title compound, (C4H7N2)2[Mn(C7H4O3)2(C4H6N2)2] [Mn(C7H4O3)2(CH4O)2]·2CH4O, there are two independent MnIII ions, each located on an inversion center. The two MnIII ions assume a distorted octahedral geometry and the complex anions are hydrogen bonded with free methylimidazolium cations and solvent methanol molecules.

scholarly journals Poly[diaquadi-μ-hydroxido-κ4O:O-dinitrato-κ4O:O′-bis[3-(pyridin-4-yl-κN)-5-(pyridin-3-yl)-1,2,4-oxadiazole]dicopper(II)]

2012 ◽  
Vol 68 (4) ◽  
pp. m422-m423 ◽  
Author(s):  
Longfei Wu ◽  
Linxia Huang ◽  
Mouhai Shu
Keyword(s):  
Hydrogen Bonds ◽  
Water Molecule ◽  
Title Compound ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Two Dimensional ◽  
Inversion Center ◽  
Centroid Distance ◽  
Distorted Octahedral ◽  
Nitrate Anions

The title compound, [Cu2(NO3)2(OH)2(C12H8N4O)2(H2O)2]n, consists of a neutral polymeric CuIIcomplex in which each CuIIatom has a distorted octahedral geometry defined by a pyridyl N atom from a 3-(pyridin-3-yl)-5-(pyridin-4-yl)-1,2,4-oxadiazole ligand and five O atoms from a water molecule, two nitrates and two hydroxides. Two CuIIions are bridged by two hydroxide anions resulting in a Cu2O2loop, located across an inversion center and connected by the nitrate anions into a broad two-dimensional polymeric structure parallel to (100). In the crystal, there are O—H...O hydrogen bonds between the coodinated water molecule and the nitrate and hydroxide, and between the hydroxide and the nitrate. Intermolecular π–π interactions are present between pyridine rings in adjacent two-dimensional structures, with a centroid–centroid distance of 3.582 (2) Å.

scholarly journals catena-Poly[[bis(pyridine-3-carboxylic acid-κN)mercury(II)]-di-μ-chlorido]

2012 ◽  
Vol 68 (4) ◽  
pp. m516-m516
Author(s):  
Sadif A. Shirvan ◽  
Sara Haydari Dezfuli
Keyword(s):  
Carboxylic Acid ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Octahedral Geometry ◽  
The Other ◽  
Distorted Octahedral Geometry ◽  
Inversion Center ◽  
Distorted Octahedral ◽  
Polymeric Chains

In the title compound, [HgCl2(C6H5NO2)2]n, the HgIIcation is located on an inversion center and is six-coordinated in a distorted octahedral geometry by two N atoms from two pyridine-3-carboxylic acid molecules and four bridging Cl−anions. The bridging function of the Cl−anions leads to polymeric chains running along theaaxis. One Hg—Cl bond is much longer than the other. In the crystal, O—H...O and weak C—H...Cl hydrogen bonds are observed.

scholarly journals Crystal structure of ammonium bis(pyridine-2,6-dicarboxylato-κ3O,N,O′)chromate(III) from synchrotron data

2015 ◽  
Vol 71 (2) ◽  
pp. 210-212 ◽  
Author(s):  
Dohyun Moon ◽  
Jong-Ha Choi
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Title Compound ◽  
Octahedral Geometry ◽  
Ammonium Cation ◽  
Distorted Octahedral Geometry ◽  
Intermolecular Hydrogen Bonds ◽  
Bond Lengths ◽  
Distorted Octahedral

The structure of the title compound, (NH4)[Cr(pydc)2] (pydc is pyridine-2,6-dicarboxylate, C7H3NO4), has been determined from synchrotron data. The CrIIIion and the N atom of the ammonium cation are located on a crystallographic fourfold rotoinversion axis (-4). The CrIIIcation is coordinated by four O atoms and the two N atoms of two meridional pydc ligands, displaying a distorted octahedral geometry. The Cr—N and Cr—O bond lengths are 1.9727 (15) and 1.9889 (9) Å, respectively. The crystal structure is stabilized by intermolecular hydrogen bonds involving the N–H groups of the ammonium cation and pyridine C–H groups as donors and the non-coordinating carbonyl O atoms as acceptors.

scholarly journals Diaquabis(2,2′-bi-1H-imidazole)manganese(II) benzene-1,4-dicarboxylate

2012 ◽  
Vol 68 (6) ◽  
pp. m829-m829
Author(s):  
Lining Yang ◽  
Yanxiang Zhi ◽  
Jiahui Hei ◽  
Yanqing Miao
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Crystal Packing ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Water Molecules ◽  
Asymmetric Unit ◽  
Π Interactions ◽  
Centroid Distance ◽  
Distorted Octahedral

The asymmetric unit of the title compound, [Mn(C6H6N4)2(H2O)2](C8H4O4), contains one-half each of the centrosymmetric cation and anion. The MnII atom is coordinated by four N atoms [Mn—N = 2.2168 (14) and 2.2407 (14) Å] from two 2,2′-biimidazole ligands and two water molecules [Mn—O = 2.2521 (14) Å] in a distorted octahedral geometry. Intermolecular N—H...O and O—H...O hydrogen bonds consolidate the crystal packing, which also exhibits π–π interactions between five-membered rings, with a centroid–centroid distance of 3.409 (2) Å.

scholarly journals Tris(ethylenediamine-κ2N,N′)cadmium hexafluoridogermanate

2012 ◽  
Vol 68 (4) ◽  
pp. m396-m397
Author(s):  
Guo-Ming Wang ◽  
Zeng-Xin Li ◽  
Pei Wang
Keyword(s):  
Hydrogen Bonds ◽  
Title Compound ◽  
Rotation Axis ◽  
Three Dimensional ◽  
Octahedral Geometry ◽  
Distorted Octahedral Geometry ◽  
Supramolecular Network ◽  
Distorted Octahedral ◽  
Axis Passing

In the title compound, [Cd(C2H8N2)3](GeF6), the CdIIatom, lying on a 32 symmetry site, is coordinated by six N atoms from three ethylenediamine (en) ligands in a distorted octahedral geometry. The Ge atom also lies on a 32 symmetry site and is coordinated by six F atoms. The en ligand has a twofold rotation axis passing through the mid-point of the C—C bond. The F atom is disordered over two sites with equal occupancy factors. In the crystal, the [Cd(en)3]2+cations and [GeF6]2−anions are connected through N—H...F hydrogen bonds, forming a three-dimensional supramolecular network.

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